Construction of Two New Metal-Organic Entangled Frameworks Via Varying Flexible Bis(Imidazole)-based Auxiliary Ligands

被引：20
作者：
Lou, Xin-Hua [1 ]
Xu, Chen [1 ]
Li, Hong-Mei [1 ]
Zhang, Zhi-Jie [1 ]
Zhang, Hao [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2013年 / 23卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Hydrothermal synthesis; Entangled framework; Mixed ligands; Luminescence; COORDINATION POLYMERS; POLYCATENATION;
D O I：
10.1007/s10904-013-9829-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two new metal-organic entangled frameworks, namely [Cd(FA)(0.5)(bix)(1.5)(H2O)] (n) center dot nNO(3) (1) and [Cd(FA)(bib)(H2O)(2)] (n) (2) (FA = fumaric acid, bix = 4,4'-bis(imidazol-1-ylmethyl)benzene, bib = 1,4-bis(imidazolyl)butane), have been successfully hydrothermally synthesized through mixed ligands strategy. Single crystal X-ray diffraction analysis reveal that 1 is a 2D -> 3D polycatenated framework, while 2 is a triply interpenetrated 4-connected dia topological net. Moreover, both compounds exhibit intense luminescence emission at room temperature.
引用
收藏
页码：659 / 664
页数：6
相关论文
共 16 条
  • [1] [Anonymous], 1997, SHELXTL 97 PROGRAM R
  • [2] Unusual parallel entanglement of metal-organic 2D frameworks with coexistence of polyrotaxane, polycatenane and interdigitation
    Cao, Xin-Yi
    Yao, Yuan-Gen
    Batten, Stuart R.
    Ma, En
    Qin, Ye-Yan
    Zhang, Jian
    Zhang, Rui-Bo
    Cheng, Jian-Kai
    [J]. CRYSTENGCOMM, 2009, 11 (06): : 1030 - 1036
  • [3] In Situ Obtained Cu(II) Compound with Coexistence of Polycatenation and Polythreading
    Cao, Xin-Yi
    Lin, Qi-Pu
    Qin, Ye-Yan
    Zhang, Jian
    Li, Zhao-Ji
    Cheng, Jian-Kai
    Yao, Yuan-Gen
    [J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (01) : 20 - 23
  • [4] Polycatenation, polythreading and polyknotting in coordination network chemistry
    Carlucci, L
    Ciani, G
    Proserpio, DM
    [J]. COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) : 247 - 289
  • [5] Borromean links and other non-conventional links in 'polycatenated' coordination polymers: re-examination of some puzzling networks
    Carlucci, L
    Ciani, G
    Proserpio, DM
    [J]. CRYSTENGCOMM, 2003, 5 : 269 - 279
  • [6] Tuning Structural Topologies of Three Photoluminescent Metal-Organic Frameworks via Isomeric Biphenyldicarboxylates
    Guo, Feng
    Wang, Fei
    Yang, Hui
    Zhang, Xiuling
    Zhang, Jian
    [J]. INORGANIC CHEMISTRY, 2012, 51 (18) : 9677 - 9682
  • [7] Synthesis, luminescence, and structural characterization of Zn and Cd coordination polymers of flexible bis(imidazolyl) derivatives
    Jin, Shouwen
    Wang, Daqi
    Chen, Wanzhi
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (06) : 685 - 689
  • [8] Varying Ligand Backbones for Modulating the Interpenetration of Coordination Polymers Based on Homoleptic Cobalt(II) Nodes
    Li, Zuo-Xi
    Xu, Yao
    Zuo, Yi
    Li, Lei
    Pan, Qinhe
    Hu, Tong-Liang
    Bu, Xian-He
    [J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (09) : 3904 - 3909
  • [9] Two non-interpenetrating 3D coordination networks with (3,4)-connected topologies
    Liu, Ying-Ying
    Ma, Ji-Cheng
    Xie, Yun-Peng
    Ma, Jian-Fang
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (21) : 3450 - 3457
  • [10] Solid-State Structural Transformations from 2D Interdigitated Layers to 3D Interpenetrated Structures
    Medishetty, Raghavender
    Koh, Lip Lin
    Kole, Goutam Kumar
    Vittal, Jagadese J.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (46) : 10949 - 10952
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