Electrochemical generation of alkyl and aryl isocyanides

被引：20

作者：

Guirado, A

Zapata, A

Gómez, JL

Trabalón, L

Gálvez, J

机构：

[1] Univ Murcia, Dept Quim Organ, Fac Quim, Murcia 30071, Spain

[2] Univ Murcia, Dept Quim Fis, Fac Quim, Murcia 30071, Spain

来源：

TETRAHEDRON | 1999年 / 55卷 / 31期

关键词：

isocyanides; carbonimidoyl dichlorides; electrochemical reduction;

D O I：

10.1016/S0040-4020(99)00509-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and widely applicable reagent-free method for the synthesis of alkyl and aryl isocyanides has been established. The electrochemical reduction of alkyl and aryl carbonimidoyl dichlorides under constant cathode potential leads to the corresponding isocyanides in almost quantitative yields. The availability of the starting materials, the mildness of the reaction conditions as well as the easy isolation of products are noteworthy, advantageous features of the procedure. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：9631 / 9640

页数：10

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