Two-dimensional inorganic networks in the crystal structures of calcium and strontium phosphite monohydrates

被引：6

作者：

Mahmoudkhani, AH ^{[1
]}

Langer, V

机构：

[1] Univ Gothenburg, Dept Chem, SE-41296 Gothenburg, Sweden

[2] Chalmers Univ Technol, Dept Inorgan Environm Chem, SE-41296 Gothenburg, Sweden

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2001年 / 176卷

关键词：

crystal structure; hydrogen bonds; layered structure; metal phosphites; metal phosphonates;

D O I：

10.1080/10426500108055105

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structures of two layered metal phosphites M(HPO3).H2O where M = Ca and Sr are reported. These compounds are the first examples of inorganic phosphites structurally related to metal phosphonates with the general formula of M(RPO3).H2O. They crystallize in monoclinic system with space group P2(1)\c and are isostructural. The structures consist of two-dimensional sheets formed by linked metal and phosphorus polyhedra, which are held together by O-H...O hydrogen bonds.

引用

页码：83 / 94

页数：12