Microphyllandiolide, a New Diterpene with an Unprecedented Skeleton from Salvia microphylla

被引：26

作者：

Bautista, Elihu ^{[1
]}

Alfredo Toscano, Ruben ^{[1
]}

Ortega, Alfredo ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 13期

关键词：

SALVINORIN;

D O I：

10.1021/ol401022c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Microphyllandiolide (1), an unprecedented rearranged clerodane-type diterpene with a 9/3 bicyclic ring system, was isolated from the aerial parts of Salvia microphylla Kunth. Its structure was elucidated by analysis of its spectroscopic data and confirmed by single crystal X-ray diffraction analysis. A possible biogenesis for microphyllandiolide (1) is proposed.

引用

页码：3210 / 3213

页数：4

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