Combustion chemistry probed by synchrotron VUV photoionization mass spectrometry

被引：359
作者：
Qi, Fei [1 ,2 ]
机构：
[1] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China
来源：
PROCEEDINGS OF THE COMBUSTION INSTITUTE | 2013年 / 34卷
关键词：
Combustion chemistry; Synchrotron VUV photoionization mass spectrometry; Pyrolysis; Oxidation; Flame; POLYCYCLIC AROMATIC-HYDROCARBONS; ION-CYCLOTRON RESONANCE; PREMIXED BENZENE/OXYGEN/ARGON FLAME; LOW-TEMPERATURE COMBUSTION; CHEMICAL KINETIC-MODELS; LOW-PRESSURE FLAME; FUEL-RICH PROPENE; X-RAY-SCATTERING; CROSS-SECTIONS; GAS-CHROMATOGRAPHY;
D O I：
10.1016/j.proci.2012.09.002
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Combustion is directly related to energy conversion and the environment. Gas-phase chemical reactions such as thermal decomposition, oxidation and recombination play a critical role in combustion processes. Here we review six applications of synchrotron vacuum-ultraviolet (VUV) photoionization mass spectrometry (PIMS) in fundamental studies of combustion chemistry. These applications range from the use of flow reactors to probe elementary reaction kinetics, studies of pyrolysis in plug-flow reactors and oxidation in jet-stirred reactors, studies of spatial evolution of species concentrations in premixed and non-premixed flames, product distributions in pyrolysis of biomass, and analysis of polycyclic aromatic hydrocarbon (PAH) formation. These experiments provide valuable data for the development and validation of detailed chemical kinetic models. Furthermore, some additional potential applications are proposed. (C) 2012 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
引用
收藏
页码：33 / 63
页数：31
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