In situ alcohol oxidation-Wittig reactions using non-stabilised phosphoranes

被引：0

作者：

Blackburn, L ^{[1
]}

Pei, CX ^{[1
]}

Taylor, RJK ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

SYNLETT | 2002年 / 02期

关键词：

alkenes; Horner-Wadsworth-Emmons; oxidation; tandem; Wittig;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New procedures have been developed which allow the in situ alcohol oxidation-Wittig reaction using manganese dioxide to be employed with non-stabilised phosphoranes and stabilised phosphonate anions. A number of examples are described utilising benzylic, allylic and propargylic alcohols.

引用

页码：215 / 218

页数：4

共 39 条

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[2] In situ manganese dioxide alcohol oxidation-Wittig reactions: Preparation of bifunctional dienyl building blocks
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JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (02): : 616 - 620
[3] The in situ oxidation-Wittig reaction of α-hydroxyketones
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[4] In situ alcohol oxidation Wittig reactions
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[5] Two carbon homologated α,β-unsaturated aldehydes from alcohols using the in situ oxidation-Wittig reaction
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TETRAHEDRON LETTERS, 2010, 51 (52) : 6890 - 6892
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JOURNAL OF CHEMICAL RESEARCH, 2014, (08) : 453 - 463
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Taylor, RJK
CHEMICAL COMMUNICATIONS, 1999, (14) : 1337 - 1338
[9] In situ alcohol oxidation-Wittig reactions using N-methoxy-N-methyl-2-(triphenylphosphoranylidine)acetamide:: application to the synthesis of a novel analogue of 5-oxo-eicosatetraenoic acid
Blackburn, L
Kanno, H
Taylor, RJK
TETRAHEDRON LETTERS, 2003, 44 (01) : 115 - 118
[10] 4-substituted protoanemonin in intramolecular cycloaddition reactions of non-stabilised azomethine ylides
Grigg, R
Savic, V
ThorntonPett, M
TETRAHEDRON, 1997, 53 (30) : 10633 - 10642

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