Ru Nanoparticles-Loaded Covalent Organic Framework for Solvent-Free One-Pot Tandem Reactions in Air

被引：78

作者：

Chen, Gong-Jun ^{[1
]}

Li, Xiao-Bo ^{[1
]}

Zhao, Chen-Chen ^{[1
]}

Ma, Hui-Chao ^{[1
]}

Kan, Jing-Lan ^{[1
]}

Xin, Yu-Bin ^{[1
]}

Chen, Cheng-Xia ^{[2
]}

Dong, Yu-Bin ^{[1
]}

机构：

[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Collaborat Innovat Ctr Functionalized Probes Chem, Key Lab Mol & Nano Probes,Minist Educ, Jinan 250014, Shandong, Peoples R China

[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Lab Bioinorgan & Synthet Chem, Lehn Inst Funct Mat, Guangzhou 510275, Guangdong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 05期

关键词：

METAL NANOPARTICLES; CATALYTIC PERFORMANCE; ASYMMETRIC CATALYSIS; COUPLING REACTION; SUZUKI-MIYAURA; HYDROGENATION; OXIDATION; SIZE; GENERATION; CONVERSION;

D O I：

10.1021/acs.inorgchem.7b03077

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Condensation of benzene-1,3,5-tricarbohydrazide with benzene-1,4-dicarboxaldehyde generated a new covalent organic framework, COF-ASB (1), in which the organic units are held together via hydrazone linkage to form porous frameworks. COF-ASB (1) is highly crystalline and displays good chemical and thermal stability and is permanently porous. In addition, 1 can be an ideal support to load Ru nanoparticles (Ru NPs) to generate Ru@COF-ASB (2). The obtained composite material is able to highly promote one-pot tandem synthesis of imine products from benzyl alcohols and corresponding amines under solvent-free conditions in air.

引用

页码：2678 / 2685

页数：8

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