Ru Nanoparticles-Loaded Covalent Organic Framework for Solvent-Free One-Pot Tandem Reactions in Air

被引：76
作者：
Chen, Gong-Jun [1 ]
Li, Xiao-Bo [1 ]
Zhao, Chen-Chen [1 ]
Ma, Hui-Chao [1 ]
Kan, Jing-Lan [1 ]
Xin, Yu-Bin [1 ]
Chen, Cheng-Xia [2 ]
Dong, Yu-Bin [1 ]
机构：
[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Collaborat Innovat Ctr Functionalized Probes Chem, Key Lab Mol & Nano Probes,Minist Educ, Jinan 250014, Shandong, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Lab Bioinorgan & Synthet Chem, Lehn Inst Funct Mat, Guangzhou 510275, Guangdong, Peoples R China
来源：
INORGANIC CHEMISTRY | 2018年 / 57卷 / 05期
关键词：
METAL NANOPARTICLES; CATALYTIC PERFORMANCE; ASYMMETRIC CATALYSIS; COUPLING REACTION; SUZUKI-MIYAURA; HYDROGENATION; OXIDATION; SIZE; GENERATION; CONVERSION;
D O I：
10.1021/acs.inorgchem.7b03077
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Condensation of benzene-1,3,5-tricarbohydrazide with benzene-1,4-dicarboxaldehyde generated a new covalent organic framework, COF-ASB (1), in which the organic units are held together via hydrazone linkage to form porous frameworks. COF-ASB (1) is highly crystalline and displays good chemical and thermal stability and is permanently porous. In addition, 1 can be an ideal support to load Ru nanoparticles (Ru NPs) to generate Ru@COF-ASB (2). The obtained composite material is able to highly promote one-pot tandem synthesis of imine products from benzyl alcohols and corresponding amines under solvent-free conditions in air.
引用
收藏
页码：2678 / 2685
页数：8
相关论文
共 51 条
  • [1] [Anonymous], 2008, MAT STUD REL NOT VER
  • [2] Metalation of a Mesoporous Three-Dimensional Covalent Organic Framework
    Baldwin, Luke A.
    Crowe, Jonathan W.
    Pyles, David A.
    McGrier, Psaras L.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (46) : 15134 - 15137
  • [3] Carbon nanodots, Ru nanodots and hybrid nanodots: preparation and catalytic properties
    Biswas, Abhijit
    Paul, Subir
    Banerjee, Arindam
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (29) : 15074 - 15081
  • [4] Dual Heterogeneous Catalyst Pd-Au@Mn(II)-MOF for One-Pot Tandem Synthesis of Imines from Alcohols and Amines
    Chen, Gong-Jun
    Ma, Hui-Chao
    Xin, Wen-Ling
    Li, Xiao-Bo
    Jin, Fa-Zheng
    Wang, Jing-Si
    Liu, Ming-Yang
    Dong, Yu-Bin
    [J]. INORGANIC CHEMISTRY, 2017, 56 (01) : 654 - 660
  • [5] Porous Organic Materials: Strategic Design and Structure-Function Correlation
    Das, Saikat
    Heasman, Patrick
    Ben, Teng
    Qiu, Shilun
    [J]. CHEMICAL REVIEWS, 2017, 117 (03) : 1515 - 1563
  • [6] Catalysis by metal nanoparticles embedded on metal-organic frameworks
    Dhakshinamoorthy, Amarajothi
    Garcia, Hermenegildo
    [J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (15) : 5262 - 5284
  • [7] The atom, the molecule, and the covalent organic framework
    Diercks, Christian S.
    Yaghi, Omar M.
    [J]. SCIENCE, 2017, 355 (6328)
  • [8] Covalent organic frameworks (COFs): from design to applications
    Ding, San-Yuan
    Wang, Wei
    [J]. CHEMICAL SOCIETY REVIEWS, 2013, 42 (02) : 548 - 568
  • [9] Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction
    Ding, San-Yuan
    Gao, Jia
    Wang, Qiong
    Zhang, Yuan
    Song, Wei-Guo
    Su, Cheng-Yong
    Wang, Wei
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (49) : 19816 - 19822
  • [10] A Photoconductive Thienothiophene-Based Covalent Organic Framework Showing Charge Transfer Towards Included Fullerene
    Dogru, Mirjam
    Handloser, Matthias
    Auras, Florian
    Kunz, Thomas
    Medina, Dana
    Hartschuh, Achim
    Knochel, Paul
    Bein, Thomas
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (10) : 2920 - 2924
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