Organometallic Diiron Complex Chemistry Related to the [2Fe]H Subsite of [FeFe]H2ase

被引：76

作者：

Capon, Jean-Francois ^{[1
,2
]}

Gloaguen, Frederic ^{[1
,2
]}

Petillon, Francois Y. ^{[1
,2
]}

Schollhammer, Philippe ^{[1
,2
]}

Talarmin, Jean ^{[1
,2
]}

机构：

[1] Univ Europeenne Bretagne, Bretagne, France

[2] Univ Brest, CNRS, UMR Chim Electrochim Mol & Chim Analyt 6521, ISSTB,CS 93837, F-29238 Brest 3, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 30卷 / 30期

关键词：

Dihydrogen; Hydrogenase; Diiron complexes; Diphosphane; Dithiolate; Hydride; Proton;

D O I：

10.1002/ejic.200800717

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

During the last decade, the structure of the subsite of [FeFe]H(2)ases (or Fe-only hydrogenases) has inspired organometallic chemists to find out whether it was possible to build synthetic molecules, based on sulfur, iron, carbon monoxide and cyanide or surrogates, having the same efficiency for hydrogen production/uptake as that of the enzyme. A short nonexhaustive overview of recent advances in this chemistry is presented. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

引用

页码：4671 / 4681

页数：11

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