Assemblies at the Liquid-Solid Interface: Chirality Expression from Molecular Conformers

被引：5

作者：

Shen, Yong-Tao ^{[1
,5
]}

Zhu, Ning-Bo ^{[3
,4
]}

Zhang, Xue-Mei ^{[1
]}

Lei, Shengbin ^{[6
,7
]}

Wei, Zhongqing ^{[2
]}

Li, Min ^{[2
]}

Zhao, Dahui ^{[3
,4
]}

Zeng, Qing-Dao ^{[1
]}

Wang, Chen ^{[1
]}

机构：

[1] Natl Ctr Nanosci & Technol NCNST, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Inst High Energy Phys, CAS Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China

[3] Peking Univ, Dept Appl Chem, BNLMS, Beijing 100871, Peoples R China

[4] Peking Univ, Key Lab Polymer Chem & Phys, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

[5] Tianjin Univ, Dept Sch Mat Sci & Engn, Tianjin Key Lab Composite & Funct Mat, Tianjin 300072, Peoples R China

[6] Harbin Inst Technol, Key Lab Microsyst & Microstruct Mfg, Minist Educ, Harbin 150080, Peoples R China

[7] Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Harbin 150080, Peoples R China

来源：

CHEMPHYSCHEM | 2013年 / 14卷 / 01期

基金：

中国国家自然科学基金;

关键词：

chirality; conformational analysis; foldamers; self-assembly; surface analysis; METAL-SURFACES; KAGOME; CRYSTALLIZATION; NETWORKS;

D O I：

10.1002/cphc.201200730

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two foldamer molecular conformers and their self-assemblies are investigated by STM at liquid/solid interfaces. A chiral structure can be obtained both from the adsorption of the two different conformers and from the assemblies formed at the liquid-solid interface. This finding suggests a convenient approach to controlling and fabricating 2D chiral nanostructures. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：92 / 95

页数：4

共 23 条

[1] [Anonymous], 2009, Angew. Chem
[2] Directing two-dimensional molecular crystallization using guest templates
Blunt, Matthew
Lin, Xiang
Gimenez-Lopez, Maria del Carmen
Schroder, Martin
Champness, Neil R.
Beton, Peter H.
[J]. CHEMICAL COMMUNICATIONS, 2008, (20) : 2304 - 2306
[3] Chiral Kagome Network from Thiacalix[4]arene Tetrasulfonate at the Interface of Aqueous Solution/Au(111) Surface: An in Situ Electrochemical Scanning Tunneling Microscopy Study
Chen, Ting
Chen, Qing
Zhang, Xu
Wang, Dong
Wan, Li-Jun
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (16) : 5598 - +
[4] DEFEYTER S, 2006, SCANNING PROBE MICRO
[5] Protein- and Peptide-Directed Syntheses of Inorganic Materials
Dickerson, Matthew B.
Sandhage, Kenneth H.
Naik, Rajesh R.
[J]. CHEMICAL REVIEWS, 2008, 108 (11) : 4935 - 4978
[6] Amplification of chirality in liquid crystals
Eelkema, Rienk
Feringa, Ben L.
[J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (20) : 3729 - 3745
[7] Molecular and Supramolecular Networks on Surfaces: From Two-Dimensional Crystal Engineering to Reactivity
Elemans, Johannes A. A. W.
Lei, Shengbin
De Feyter, Steven
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (40) : 7298 - 7332
[8] Two-dimensional chirality at liquid-solid interfaces
Elemans, Johannes A. A. W.
De Cat, Inge
Xu, Hong
De Feyter, Steven
[J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (03) : 722 - 736
[9] Supramolecular surface chirality
Ernst, Karl-Heinz
[J]. SUPRAMOLECULAR CHIRALITY, 2006, 265 : 209 - 252
[10] Molecular geometry directed Kagome and honeycomb networks: Toward two-dimensional crystal engineering
Furukawa, S
Uji-i, H
Tahara, K
Ichikawa, T
Sonoda, M
De Schryver, FC
Tobe, Y
De Feyter, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (11) : 3502 - 3503

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