Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf=1,1′-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

被引：106

作者：

Ghosh, Shishir ^{[1
]}

Hogarth, Graeme ^{[1
,2
]}

Hollingsworth, Nathan ^{[1
]}

Holt, Katherine B. ^{[1
]}

Kabir, Shariff E. ^{[3
]}

Sanchez, Ben E. ^{[1
]}

机构：

[1] Univ London Univ Coll, Dept Chem, London WC1H 0AJ, England

[2] Kings Coll London, Dept Chem, London SE1 1DB, England

[3] Jahangirnagar Univ, Dept Chem, Dhaka 1342, Bangladesh

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 08期

基金：

英国工程与自然科学研究理事会;

关键词：

IRON-ONLY HYDROGENASE; CRYSTAL-STRUCTURE; 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE DPPF; HETEROPOLYMETALLIC COMPLEXES; STRUCTURAL-CHARACTERIZATION; PHOSPHINE LIGAND; FE-HYDROGENASE; H-2; EVOLUTION; MODELS; BRIDGE;

D O I：

10.1039/c3cc46456c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fe-2(CO)(4)(mu-dppf)(mu-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.

引用

页码：945 / 947

页数：3

共 43 条

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