Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf=1,1′-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

被引：106
作者：
Ghosh, Shishir [1 ]
Hogarth, Graeme [1 ,2 ]
Hollingsworth, Nathan [1 ]
Holt, Katherine B. [1 ]
Kabir, Shariff E. [3 ]
Sanchez, Ben E. [1 ]
机构：
[1] Univ London Univ Coll, Dept Chem, London WC1H 0AJ, England
[2] Kings Coll London, Dept Chem, London SE1 1DB, England
[3] Jahangirnagar Univ, Dept Chem, Dhaka 1342, Bangladesh
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 08期
基金：
英国工程与自然科学研究理事会;
关键词：
IRON-ONLY HYDROGENASE; CRYSTAL-STRUCTURE; 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE DPPF; HETEROPOLYMETALLIC COMPLEXES; STRUCTURAL-CHARACTERIZATION; PHOSPHINE LIGAND; FE-HYDROGENASE; H-2; EVOLUTION; MODELS; BRIDGE;
D O I：
10.1039/c3cc46456c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Fe-2(CO)(4)(mu-dppf)(mu-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.
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页码：945 / 947
页数：3
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