Heterometallic Complexes of Co2+, Ni2+, and Zn2+ with the [RuNO(NO2)4OH]2- Anion and Pyridine: Synthesis, Crystal Structure, and Thermolysis

被引：12
|
作者：
Kostin, G. A. [1 ]
Borodin, A. O. [1 ]
Shubin, Yu. V. [1 ]
Kurat'eva, N. V. [1 ]
Emelyanov, V. A. [1 ]
Plyusnin, P. E. [1 ]
Gallyamov, M. R. [2 ]
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 35卷 / 01期
关键词：
NITROSYLRUTHENIUM; PRECURSORS; PRODUCTS; LIGANDS; OXIDES;
D O I：
10.1134/S1070328409010126
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new heteronuclear complexes [Ru(NO)(NO2)(4)(OH)M(Py)(3)] (M = Co2+,Ni2+,Zn2+) were synthesized and structurally characterized. In all compounds, the [Ru(NO)(NO2)(4)(OH)] fragment is coordinated to the M atom by a bridging OH and two bridging NO2 groups. The coordination environment of the metal also includes three pyridine nitrogen atoms. Thermal decomposition of cobalt and nickel complexes in an inert atmosphere yields bimetallic solid solutions.
引用
收藏
页码：57 / 64
页数：8
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