Synthesis and structural characterization of imido-lanthanide complexes with a metal-nitrogen multiple bond

被引：74

作者：

Chan, HS ^{[1
]}

Li, HW ^{[1
]}

Xie, ZW ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b110793c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of an amido-ytterbium complex with n-BuLi leads to the isolation and structural characterization of a mixed amido-imido-ytterbium or imido-ytterbium complex, respectively, depending upon the molar ratios of the reactants; the Yb-N distance and the linearity of the imido N atom strongly suggest the presence of a formal Yb=N multiple bond in these novel complexes.

引用

页码：652 / 653

页数：2

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