Preparation, structure and conductivity of Et(2)Me(2)Z (Z=P,As,Sb) salts of M(dmit)(2) and M(dmise)(2) (M=Ni,Pd)

被引：22

作者：

Aonuma, S

Sawa, H

Kato, R

机构：

来源：

SYNTHETIC METALS | 1997年 / 86卷 / 1-3期

关键词：

organic conductors based on radical cation and/or anion salts metal-insulator phase transition; conductivity; x-ray diffraction; semi-empirical models and model calculations;

D O I：

10.1016/S0379-6779(97)80950-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Et2Me2P+ was synthesized by Grignard reaction of MePCl2 with EtMgBr, followed by quaternarization using Mel. Et2Me2Sb+ was prepared by similar method, but obtained as mixture of EtnMe(4-n)Sb+(n=0, 1, 2, 3). Fortunately, (Et2Me2Sb) [Pd(dmit)(2)](2) could be obtained as single crystals in a certain condition. Both (Et2Me2P) [Pd(dmit)(2)](2) and (Et2Me2Sb)[Pd(dmit)(2)](2) are isostructural with beta'-Me(4)Z salts (Z=P, As, Sb), and indicate stronger dimerisation and enhanced two-dimensionality.

引用

页码：1881 / 1882

页数：2

共 4 条

[1] MOLECULAR-METALS AND SUPERCONDUCTORS DERIVED FROM METAL-COMPLEXES OF 1,3-DITHIOL-2-THIONE-4,5-DITHIOLATE (DMIT) [J].