Preparation and photocatalytic properties of Cu2ZnSnS4for H2production

被引:13
作者
Wang, Jiansheng [1 ]
Zeng, Xiongfeng [1 ]
Zhao, Yingna [1 ]
Zhang, Wenli [1 ]
机构
[1] North China Univ Sci & Technol, Coll Mat Sci & Engn, Tangshan 063210, Peoples R China
关键词
Cu2ZnSnS4; (CZTS); thin film; ultrasonic spray pyrolysis; photocatalytic water splitting; hydrogen production; CHARGE SEPARATION; CU2ZNSNS4; WATER; HYDROGEN; SEMICONDUCTOR; PERFORMANCE; REDUCTION; FILMS;
D O I
10.1088/2053-1591/abba9d
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Cu2ZnSnS4(CZTS) thin film photocatalytic water splitting for hydrogen production under visible light irradiation has been reported together with CZTS nanoparticles prepared by ultrasonic spray pyrolysis and hydrothermal method, respectively. CZTS thin film provided higher H(2)production rate (68.68 mu mol g(-1) h(-1)), which was 32 times higher than that of CZTS nanoparticles (2.08 mu mol g(-1) h(-1)) without loading any noble metals. What's more, photocatalytic activity of CZTS thin film remained 94% after 48 h which confirmed the good stability and reusability of CZTS thin film. CZTS thin film is a potential and durable candidate for photocatalysis.
引用
收藏
页数:7
相关论文
共 23 条
  • [1] High temperature recrystallization of kersterite Cu2ZnSnS4 towards enhanced photocatalytic H2 evolution
    Chang, Zhi-Xian
    Chong, Rui-Feng
    Meng, Yue-Na
    Zhou, Wen-Hui
    Kou, Dong-Xing
    Zhou, Zheng-Ji
    Wu, Si-Xin
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (39) : 13456 - 13462
  • [2] Characterization of a CZTS thin film solar cell grown by sputtering method
    Dhakal, Tara P.
    Peng, Chien-Yi
    Tobias, R. Reid
    Dasharathy, Ramesh
    Westgate, Charles R.
    [J]. SOLAR ENERGY, 2014, 100 : 23 - 30
  • [3] Hydrogen production by photocatalytic water-splitting using Cr- or Fe-doped TiO2 composite thin films photocatalyst
    Dholam, R.
    Patel, N.
    Adami, M.
    Miotello, A.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (13) : 5337 - 5346
  • [4] Structural design of TiO2-based photocatalyst for H2 production and degradation applications
    Gao, Minmin
    Zhu, Liangliang
    Ong, Wei Li
    Wang, Jing
    Ho, Ghim Wei
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (10) : 4703 - 4726
  • [5] Quaternary semiconductor Cu2ZnSnS4 loaded with MoS2 as a co-catalyst for enhanced photo-catalytic activity
    Gogoi, Gaurangi
    Arora, Sonia
    Vinothkumar, Natarajan
    De, Mahuya
    Qureshi, Mohammad
    [J]. RSC ADVANCES, 2015, 5 (51): : 40475 - 40483
  • [6] Significant Enhancement in Photocatalytic Reduction of Water to Hydrogen by Au/Cu2ZnSnS4 Nanostructure
    Ha, Enna
    Lee, Lawrence Yoon Suk
    Wang, Jingchuan
    Li, Fenghua
    Wong, Kwok-Yin
    Tsang, Shik Chi Edman
    [J]. ADVANCED MATERIALS, 2014, 26 (21) : 3496 - 3500
  • [7] Visible light photocatalytic H2-production activity of epitaxial Cu2ZnSnS4/ZnS heterojunction
    Jiang, Fan
    Pan, Bao
    You, Daotong
    Zhou, Yangen
    Wang, Xuxu
    Su, Wenyue
    [J]. CATALYSIS COMMUNICATIONS, 2016, 85 : 39 - 43
  • [8] Efficient hydrogen/oxygen evolution and photocatalytic dye degradation and reduction of aqueous Cr(VI) by surfactant free hydrophilic Cu2ZnSnS4 nanoparticles
    Kush, Priya
    Deori, Kalyanjyoti
    Kumar, Anup
    Deka, Sasanka
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (15) : 8098 - 8106
  • [9] Matthews T S, 2013, GROWTH CHARACTERIZAT
  • [10] Recent progress on perovskite materials in photovoltaic and water splitting applications
    Moniruddin, Md
    Ilyassov, Baurzhan
    Zhao, Xiao
    Smith, Eric
    Serikov, Timur
    Ibrayev, Niyazbek
    Asmatulu, Ramazan
    Nuraje, Nurxat
    [J]. MATERIALS TODAY ENERGY, 2018, 7 : 246 - 259