Enantiomeric resolution of chiral sulfoxides on polysaccharide phases by HPLC

被引：0
作者：
Matlin, SA
Tiritan, ME
Cass, QB
Boyd, DR
机构：
[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND
[2] UNIV FED SAO CARLOS,DEPT CHEM,SAO CARLOS,SP,BRAZIL
[3] QUEENS UNIV BELFAST,SCH CHEM,BELFAST,ANTRIM,NORTH IRELAND
来源：
CHIRALITY | 1996年 / 8卷 / 01期
关键词：
amylose; (S)-alpha-methylbenzyl carbamate; chiral sulfoxides; microporous silica; polysaccharide phases;
D O I：
10.1002/(SICI)1520-636X(1996)8:1<147::AID-CHIR22>3.0.CO;2-M
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
The enantiomeric resolution of chiral sulfoxides was investigated on amylose (S)-alpha-methylbenzyl carbamate phase coated on aminopropylated 7 mu m silica with 500 Angstrom diameter pores. This was shown to be very successful in the separation of alkyl/aryl, aryl/aryl, and non-aromatic sulfoxides. The effect of pore size using naked silica was also investigated, demonstrating that the pore size does not affect the resolution. (C) 1996 Wiley-Liss, Inc.
引用
收藏
页码：147 / 152
页数：6
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