Photo catalytic degradation of linear alkylbenzene sulfonic acid

被引:9
作者
Ahmari, Hadi [1 ]
Heris, Saeed Zeinali [1 ]
Khayyat, Mohammad Hassanzadeh [2 ]
机构
[1] Ferdowsi Univ Mashhad, Dept Chem Engn, Fac Engn, Mashhad, Iran
[2] Univ Med Sci, Dept Pharmaceut Chem, Pharmaceut Sci Res Ctr, Mashhad, Iran
关键词
Linear alkylbenzene sulfonic acid; Photodegradation; TiO2; nanoparticles; Coaxial cylinders; PHOTOCATALYTIC ACTIVITY; TIO2; LAS; SURFACTANTS; BIODEGRADATION; OPTIMIZATION; REMOVAL; DESIGN;
D O I
10.1007/s11164-016-2483-1
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Linear alkylbenzene sulfonic acid (LAS) is a common substance used in the production of detergents in the world. This is an organic material with its structure made of benzene ring and double bonds. This structure creates many problems for the environment and humans. Up to now, various methods have been used to eliminate this pollution. A recently proposed method to remove this organic pollution is advanced oxidation processes. Photocatalytic degradation is also an efficient method to destroy organic structures. In this research, TiO2 nanoparticles are used as a photocatalyst that is activated by UV irradiation. TiO2 nanoparticles and pollution suspension are incorporated into the new design of the reactor with coaxial cylinders in which the inner cylinder rotates at a constant speed. The results show that in low concentrations of LAS, using TiO2 nanoparticles, the time to reach pollution elimination is reduced significantly. In higher concentrations of LAS, UV irradiation is more effective than activated TiO2 nanoparticles.
引用
收藏
页码:6587 / 6606
页数:20
相关论文
共 43 条
[1]   Degradation of pesticides chlorpyrifos, cypermethrin and chlorothalonil in aqueous solution by TiO2 photocatalysis [J].
Affam, Augustine Chioma ;
Chaudhuri, Malay .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2013, 130 :160-165
[2]  
Ahmari H, 2015, BULG CHEM COMMUN, V47, P491
[3]   Biodegradation of the Anionic Surfactant Linear Alkylbenzene Sulfonate (LAS) by Autochthonous Pseudomonas sp. [J].
Asok, Aju K. ;
Jisha, M. S. .
WATER AIR AND SOIL POLLUTION, 2012, 223 (08) :5039-5048
[4]   Full factorial experimental design applied to oxalic acid photocatalytic degradation in TiO2 aqueous suspension [J].
Barka, N. ;
Abdennouri, M. ;
Boussaoud, A. ;
Galadi, A. ;
Baalala, M. ;
Bensitel, M. ;
Sahibed-Dine, A. ;
Nohair, K. ;
Sadiq, M. .
ARABIAN JOURNAL OF CHEMISTRY, 2014, 7 (05) :752-757
[5]  
Branner U, 1999, ENVIRON TOXICOL CHEM, V18, P1772, DOI [10.1897/1551-5028(1999)018<1772:DOLASI>2.3.CO
[6]  
2, 10.1002/etc.5620180824]
[7]   MEASUREMENT OF LINEAR ALKYLBENZENESULFONATES IN AQUEOUS ENVIRONMENTAL MATRICES BY LIQUID-CHROMATOGRAPHY WITH FLUORESCENCE DETECTION [J].
CASTLES, MA ;
MOORE, BL ;
WARD, SR .
ANALYTICAL CHEMISTRY, 1989, 61 (22) :2534-2540
[8]   Preparation of size-controlled TiO2 nanoparticles and derivation of optically transparent photocatalytic films [J].
Chae, SY ;
Park, MK ;
Lee, SK ;
Kim, TY ;
Kim, SK ;
Lee, WI .
CHEMISTRY OF MATERIALS, 2003, 15 (17) :3326-3331
[9]   Fighting global warming by photocatalytic reduction of CO2 using giant photocatalytic reactors [J].
de Richter, Renaud Kiesgen ;
Ming, Tingzhen ;
Caillol, Sylvain .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2013, 19 :82-106
[10]  
Ebrahimi A., 2015, INT J ENV HLTH ENG, V4, P10, DOI DOI 10.4103/2277-9183.163973