Luminescence properties of ZrO2 mesoporous thin films doped with Eu3+ and Agn

被引：13

作者：

Leroy, C. M. ^{[1
]}

Cardinal, T. ^{[1
]}

Jubera, V. ^{[1
]}

Aymonier, C. ^{[1
]}

Treguer-Delapierre, M. ^{[1
]}

Boissiere, C. ^{[2
]}

Grosso, D. ^{[2
]}

Sanchez, C. ^{[2
]}

Viana, B. ^{[2
]}

Pelle, F. ^{[2
]}

机构：

[1] Univ Bordeaux, CNRS, ICMCB, F-33608 Pessac, France

[2] Chim Matiere Condensee Paris UPMC ENSCP, F-75252 Paris, France

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2013年 / 170卷

关键词：

Europium; Zirconia; Films; Silver; Nanoparticles; PLANAR WAVE-GUIDES; SOL-GEL PROCESS; OPTICAL-PROPERTIES; SUPERCRITICAL FLUIDS; ZIRCONIA; EUROPIUM; NANOPARTICLES; NANOCRYSTALS; TEMPERATURE; DEPOSITION;

D O I：

10.1016/j.micromeso.2012.11.014

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Rare earth doped zirconium oxides are of interest as active materials in high-performance luminescent devices. Transparent ZrO2:Eu3+ mesoporous thin films with different doping ion concentrations were prepared by Evaporation Induced Self Assembly (EISA). The films exhibited high specific area and periodicity through connected networks of nanometer scaled pores. Thermal treatments at 600 degrees C allowed the conversion of amorphous films into semi-crystalline ones. A detailed analysis of the structural and optical characterizations revealed that the Eu3+ ions sit inside the ZrO2 tetragonal crystallites as well as in the enriched zirconia amorphous phase of the walls nanoarchitecture. The introduction of silver nanoparticles in the porous network allowed to a strong modulation of the photoluminescence emission intensity. (C) 2012 Elsevier Inc. All rights reserved.

引用

页码：123 / 130

页数：8

共 42 条

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