Electrospun smart fabrics that display pH-responsive tunable wettability

被引:32
作者
Lee, Chang Hwan [2 ,3 ]
Kang, Sung Kyung [4 ]
Lim, Jung Ah [5 ]
Lim, Ho Sun [1 ]
Cho, Jeong Ho [2 ,3 ]
机构
[1] Korea Elect Technol Inst, Elect Mat & Device Res Ctr, Gyeonggi Do 463816, South Korea
[2] Sungkyunkwan Univ, SKKU Adv Inst Nanotechnol SAINT, Suwon 440746, South Korea
[3] Sungkyunkwan Univ, Ctr Human Interface Nano Technol HINT, Dept Chem Engn, Suwon 440746, South Korea
[4] Soongsil Univ, Dept Organ Mat & Fiber Engn, Seoul 156743, South Korea
[5] Korea Inst Sci & Technol, Future Convergence Res Div, Seoul 136791, South Korea
关键词
SURFACE; SUPERHYDROPHILICITY; SUPERHYDROPHOBICITY; POLYMERIZATION; ADSORPTION; MORPHOLOGY; TERTIARY; DELIVERY; FIBERS;
D O I
10.1039/c2sm26625c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Smart fabrics that reversibly switch between superhydrophobicity and superhydrophilicity were developed using a combination of hierarchical nanostructured fibrous webs and a pH-responsive polymer that experiences pH-dependent conformational transitions, poly[2-(diisopropylamino) ethylmethacrylate-co-3-(trimethoxysilyl) propylmethacrylate].
引用
收藏
页码:10238 / 10240
页数:3
相关论文
共 34 条
[1]   POTENTIAL-DEPENDENT WETTING OF AQUEOUS-SOLUTIONS ON SELF-ASSEMBLED MONOLAYERS FORMED FROM 15-(FERROCENYLCARBONYL)PENTADECANETHIOL ON GOLD [J].
ABBOTT, NL ;
WHITESIDES, GM .
LANGMUIR, 1994, 10 (05) :1493-1497
[2]   Tunable, superhydrophobically stable polymeric surfaces by electrospinning [J].
Acatay, K ;
Simsek, E ;
Ow-Yang, C ;
Menceloglu, YZ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (39) :5210-5213
[3]   Synthesis and aqueous solution properties of near-monodisperse tertiary amine methacrylate homopolymers and diblock copolymers [J].
Bütün, V ;
Armes, SP ;
Billingham, NC .
POLYMER, 2001, 42 (14) :5993-6008
[4]   pH-Responsive polymers: synthesis, properties and applications [J].
Dai, Sheng ;
Ravi, Palaniswamy ;
Tam, Kam Chiu .
SOFT MATTER, 2008, 4 (03) :435-449
[5]   Spinning continuous fibers for nanotechnology [J].
Dzenis, Y .
SCIENCE, 2004, 304 (5679) :1917-1919
[6]   Reversible control of free energy and topography of nanostructured surfaces [J].
Fu, Q ;
Rao, GVR ;
Basame, SB ;
Keller, DJ ;
Artyushkova, K ;
Fulghum, JE ;
López, GP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :8904-8905
[7]   Phosphorylcholine-based pH-responsive diblock copolymer micelles as drug delivery vehicles: Light scattering, electron microscopy, and fluorescence experiments [J].
Giacomelli, C ;
Le Men, L ;
Borsali, R ;
Lai-Kee-Him, J ;
Brisson, A ;
Armes, SP ;
Lewis, AL .
BIOMACROMOLECULES, 2006, 7 (03) :817-828
[8]  
Ingold S. C., 1969, STRUCTURE MECH ORGAN
[9]   Atomic force microscopic analysis of a porous membrane with pH-sensitive molecular valves [J].
Iwata, H ;
Hirata, I ;
Ikada, Y .
MACROMOLECULES, 1998, 31 (11) :3671-3678
[10]   A lotus-leaf-like superhydrophobic surface: A porous microsphere/nanofiber composite film prepared by electrohydrodynamics [J].
Jiang, L ;
Zhao, Y ;
Zhai, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (33) :4338-4341