Synthesis and structures of new C60 fullerene derivatives containing carbonyl groups

被引：3

作者：

Gubskaya, VP ^{[1
]}

Sibgatullina, FG ^{[1
]}

Yanilkin, VV ^{[1
]}

Morozov, VI ^{[1
]}

Toropchina, AV ^{[1
]}

Zverev, VV ^{[1
]}

Azancheev, NM ^{[1
]}

Nuretdinov, IA ^{[1
]}

机构：

[1] Russian Acad Sci, AE Arbuzov Inst Organ & Phys Chem, Kazan Res Ctr, Kazan 420088, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2005年 / 54卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

fullerene C-60; methanofullerenes; haloketones; Bingel reaction; high-performance liquid chromatography; H-1 and C-13 NMR spectroscopy; UV spectroscopy; IR spectroscopy; MALDI TOF mass spectrometry; cyclic voltammetry; ESR spectroscopy; quantum-chemical calculations; PM3 and DFT/PBE/TZ2P methods;

D O I：

10.1007/s11172-005-0428-8

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of fullerene C-60 With substituted haloketones, including organophosphorus haloketones, in the presence of bases afforded new methanofullerenes containing carbonyl or carbonyl and acetal groups. The structures of the resulting compounds were established by spectroscopic methods. Their electrochemical reduction and oxidation were studied by cyclic voltammetry and ESR spectroscopy. The three-dimensional structures were calculated by the PM3 and DFT/PBE/TZ2P methods.

引用

页码：1467 / 1472

页数：6

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