Oxidative cleavage of oximes with silica-gel-supported chromic acid in nonaqueous media

被引:14
作者
Ali, Mohammed Hashmat [1 ]
Greene, Stacie [1 ]
Wiggin, Candace J. [1 ]
Khan, Saira [1 ]
机构
[1] SE Missouri State Univ, Dept Chem, Cape Girardeau, MO 63701 USA
关键词
chromic acid; chromic acid-SiO2; deoximation; solid support;
D O I
10.1080/00397910600616966
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A simple procedure for a clean and high-yielding oxidative deoximation of benzaldoximes and ketoximes using a silica-gel-supported chromic acid reagent has been developed. This solid-supported reagent allows us to carry out this reaction in nonaqueous dichloromethane reaction media.
引用
收藏
页码:1761 / 1767
页数:7
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