Effects of PVA fibers on microstructures and hydration products of cementitious composites with and without fly ash

被引:21
作者
Shen, Yinong [1 ]
Li, Qinghua [1 ]
Huang, Botao [1 ]
Liu, Xin [1 ]
Xu, Shilang [1 ]
机构
[1] Zhejiang Univ, Inst Adv Engn Struct, Hangzhou 310058, Peoples R China
基金
中国国家自然科学基金;
关键词
Fibers; Cement; Fly ash; Hydration; Microstructure; C-S-H; MICRO-CRACKED ECC; BLENDED CEMENT; PORTLAND-CEMENT; MECHANICAL-PROPERTIES; PORE STRUCTURE; SILICATE; STRENGTH; VOLUME; NMR;
D O I
10.1016/j.conbuildmat.2022.129533
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
This study explores the effects of poly(vinyl alcohol) (PVA) fibers on the microstructures and hydration products of cementitious composites with and without high-volume fly ash. To this end, the prepared composites are systematically characterized. The results indicate significant differences in the effect of PVA fibers on the cementitious composites with different fly ash contents. In the cementitious composites with high-volume fly ash, the PVA fibers give rise to the decalcification and polymerization of calcium (alumino) silicate hydrate (C (-A)-S-H) gels and a looser gel pore structure. In the composites without fly ash, PVA fibers promote the formation of Ca(OH)2 on the surface of fibers, increase the calcium-to-silicon ratio, and refine the gel pore structure. Furthermore, this study provides new insights into the influence of PVA fibers on the pore structure and molecular structure of the cementitious composites with different fly ash contents associated with their durability and dielectric properties.
引用
收藏
页数:13
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共 67 条
[1]   Characterization of white Portland cement hydration and the C-S-H structure in the presence of sodium aluminate by 27Al and 29Si MAS NMR spectroscopy [J].
Andersen, MD ;
Jakobsen, HJ ;
Skibsted, J .
CEMENT AND CONCRETE RESEARCH, 2004, 34 (05) :857-868
[2]   Effect of the hydration temperature on the microstructure of Class G cement: C-S-H composition and density [J].
Bahafid, Sara ;
Ghabezloo, Siavash ;
Duc, Myriam ;
Faure, Pamela ;
Sulem, Jean .
CEMENT AND CONCRETE RESEARCH, 2017, 95 :270-281
[3]   Effective cation exchange capacity of calcium silicate hydrates (C-S-H) [J].
Bernard, Ellina ;
Yan, Yiru ;
Lothenbach, Barbara .
CEMENT AND CONCRETE RESEARCH, 2021, 143
[4]   Characterisation of crystalline C-S-H phases by X-ray photoelectron spectroscopy [J].
Black, L ;
Garbev, K ;
Stemmermann, P ;
Hallam, KR ;
Allen, GC .
CEMENT AND CONCRETE RESEARCH, 2003, 33 (06) :899-911
[5]   Surface carbonation of synthetic C-S-H samples: A comparison between fresh and aged C-S-H using X-ray photoelectron spectroscopy [J].
Black, Leon ;
Garbev, Krassimir ;
Gee, Ian .
CEMENT AND CONCRETE RESEARCH, 2008, 38 (06) :745-750
[6]   The crystal structure of tobermorite 14 A (Plombierite), a C-S-H phase [J].
Bonaccorsi, E ;
Merlino, S ;
Kampf, AR .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (03) :505-512
[7]   Bridging the gap between NMR measured mean silicate chain length and nano-scale silicate polymorphism of calcium silicate hydrates [J].
Chiang, Yuan ;
Chang, Shu-Wei .
CEMENT AND CONCRETE RESEARCH, 2021, 140
[8]   Effect of fly ash fineness on compressive strength and pore size of blended cement paste [J].
Chindaprasirt, P ;
Jaturapitakkul, C ;
Sinsiri, T .
CEMENT & CONCRETE COMPOSITES, 2005, 27 (04) :425-428
[9]   Local structure and Ca/Si ratio in C-S-H gels from hydration of blends of tricalcium silicate and silica fume [J].
Cuesta, Ana ;
Santacruz, Isabel ;
De la Torre, Angeles G. ;
Dapiaggi, Monica ;
Zea-Garcia, Jesus D. ;
Aranda, Miguel A. G. .
CEMENT AND CONCRETE RESEARCH, 2021, 143
[10]   Characterization of mullite in silicoaluminous fly ash by XRD, TEM, and 29Si MAS NMR [J].
Gomes, S ;
François, M .
CEMENT AND CONCRETE RESEARCH, 2000, 30 (02) :175-181