Study of electrodeposition of amorphous Sn-Ni-Fe ternary alloys from a gluconate based electrolyte

被引：13

作者：

Sziraki, L. ^{[1
]}

Kuzmann, E. ^{[1
]}

Lak, G. B. ^{[1
,2
]}

El-Sharif, M. ^{[2
]}

Chisholm, C. U. ^{[2
]}

Stichleutner, S. ^{[1
,3
]}

Havancsak, K. ^{[4
]}

Zih-Perenyi, K. ^{[1
]}

Homonnay, Z. ^{[1
]}

Vertes, A. ^{[1
]}

机构：

[1] Eotvos L Univ, Inst Chem, H-1518 Budapest, Hungary

[2] Glasgow Caledonian Univ, Glasgow G4 0BA, Lanark, Scotland

[3] HAS, Inst Isotopes, H-1525 Budapest, Hungary

[4] Eotvos L Univ, Inst Phys, H-1518 Budapest, Hungary

来源：

SURFACE & COATINGS TECHNOLOGY | 2012年 / 211卷

基金：

匈牙利科学研究基金会;

关键词：

Sn-Fe-Ni ternary alloy; Electrodeposition; Fe-57 and Sn-119 Mossbauer spectroscopy; X-ray diffraction; SEM; AFM; TIN ELECTRODEPOSITION; ANODES;

D O I：

10.1016/j.surfcoat.2011.09.024

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Novel Sn-Ni-Fe ternary phases, which never occur in the metallurgical alloys, were successfully prepared by deposition from an electrolyte based on sodium gluconate, using DC electrodeposition conditions. Fe-57 and Sn-119 conversion electron Mossbauer spectroscopy and PXRD investigations of these alloys showed that they are amorphous and dominantly ferromagnetic. The occurrence of amorphous Sn-Fe-Ni ternary alloy phase in deposits was found to increase with the current density applied during the deposition. The co-deposition kinetics is mainly governed by the electrodeposition behavior of the tin-gluconate complex that forms in the electrolyte. The high cathodic polarization due to the tin-gluconate discharge causes an apparent mass transfer coupled co-deposition of iron. The nickel deposition rate is independent of the potential and of the partial current of the co-depositing species. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：184 / 187

页数：4

共 18 条

[1]

[Anonymous], 1958, Constitution of Binary Alloys

[2] Preparation and characterisation of electrodeposited amorphous Sn-Co-Fe ternary alloys [J].