Rapid in-situ solidification of SiO2 suspension by direct coagulation casting via controlled release of high valence counter ions from calcium iodate and pH shift

Rapid in-situ solidification of SiO2 suspension under the joint action of releasing calcium ions and shifting pH has been proposed. When the suspension was heated up to 60 degrees C, decomposition of calcium iodate which released calcium ions, as well as hydrolysis of diacetate (GDA) which shifted the pH toward the isoelectric point, both contributed to the solidification of suspension. The controlled coagulation of SiO2 suspension could be realized via controlled release of high valence counter ions and pH shift at 60 degrees C within 30 min, which could considerably shorten the coagulation time compared with present reported results (1-3 h). Green body prepared by heating the SiO2 suspension with 6.5 g L-1 calcium iodate and 2.0 vol% GDA at 60 C for 30 min shows uniform microstructure with compressive strength of close to 0.3 MPa. SiO2 ceramics sintered at 1275 C for 3 h possess homogeneous microstructure with bulk density of 2.06 g cm(-3) and flexural strength of 40.3 MPa.