Production of ionic liquids by electrodialysis

被引：38
|
作者：
Haerens, Kurt [1 ,2 ]
De Vreese, Peter [1 ]
Matthijs, Edward [1 ]
Pinoy, Luc [1 ]
Binnemans, Koen [3 ]
Van der Bruggen, Bart [2 ]
机构：
[1] KaHo Sint Lieven, Lab Chem Proc Technol, Dept Ind Engn, B-9000 Ghent, Belgium
[2] Katholieke Univ Leuven, Lab Appl Phys Chem & Environm Technol, Dept Chem Engn, B-3001 Heverlee, Belgium
[3] Katholieke Univ Leuven, Lab Coordinat Chem, Dept Chem, B-3001 Heverlee, Belgium
来源：
SEPARATION AND PURIFICATION TECHNOLOGY | 2012年 / 97卷
关键词：
Ionic liquids; Choline; Electrodialysis; Metathesis; Halide impurities; THERMAL-DEGRADATION; EXCHANGE MEMBRANES; TEMPERATURE; WATER; SEPARATION; SALTS; PURIFICATION; STABILITY; VISCOSITY; SOLVENTS;
D O I：
10.1016/j.seppur.2012.02.017
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Electrodialysis is an environmentally friendly method for the synthesis of hydrophilic ionic liquids. This synthetic method is much easier to scale up than ion-exchange processes. Choline thiocyanate, choline acetate and choline dicyanamide have been prepared by electrodialysis from the inexpensive starting product choline chloride. Current efficiencies between 65% and 78% were obtained. The purity of the ionic liquids was found to be strongly influenced by the purity of the starting products. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：90 / 95
页数：6
相关论文
共 50 条
  • [1] Transport Properties of Various Ionic Liquids During Electrodialysis
    Takatsugu Endo
    Koji Osawa
    Mai Tatsumi
    Kazuaki Ninomiya
    Kenji Takahashi
    Journal of Solution Chemistry, 2015, 44 : 2405 - 2415
  • [2] Transport Properties of Various Ionic Liquids During Electrodialysis
    Endo, Takatsugu
    Osawa, Koji
    Tatsumi, Mai
    Ninomiya, Kazuaki
    Takahashi, Kenji
    JOURNAL OF SOLUTION CHEMISTRY, 2015, 44 (12) : 2405 - 2415
  • [3] Preparation of water-soluble ionic liquids by electrodialysis
    Yang, Lanlan
    Liu, Lifen
    Li, Yiming
    Mao, Peiqing
    Xu, Danqian
    Huagong Xuebao/CIESC Journal, 2009, 60 (07): : 1837 - 1842
  • [4] Electrodialysis To Concentrate Waste Ionic Liquids: Optimization of Operating Parameters
    Yan, Haiyang
    Xu, Chunyan
    Li, Wei
    Wang, Yaoming
    Xu, Tongwen
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2016, 55 (07) : 2144 - 2152
  • [5] Recovery of ionic liquids from dilute aqueous solutions by electrodialysis
    Wang, Xiaoliang
    Nie, Yi
    Zhang, Xiangping
    Zhang, Suojiang
    Li, Jianwei
    DESALINATION, 2012, 285 : 205 - 212
  • [6] Competitive transport of ionic liquids and impurity ions during the electrodialysis process
    Li, Hui
    Meng, Hong
    Li, Chunxi
    Li, Liangshi
    DESALINATION, 2009, 245 (1-3) : 349 - 356
  • [7] Production of alkylated gasoline using ionic liquids and immobilized ionic liquids
    Kumar, Prashant
    Vermeiren, Walter
    Dath, Jean-Pierre
    Hoelderich, Wolfgang F.
    APPLIED CATALYSIS A-GENERAL, 2006, 304 (01) : 131 - 141
  • [8] Ionic Liquids for Biodiesel Production
    不详
    CHEMSUSCHEM, 2011, 4 (02) : 170 - 170
  • [9] ELECTRODIALYSIS OF POLAR SOLVANTS .6. IONIC PURIFICATION OF APROTIC LIQUIDS
    BRIERE, G
    ROSE, B
    JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1967, 64 (11-1) : 1720 - &
  • [10] Synthesis of [EMIM]OH via bipolar membrane electrodialysis -: precursor production for the combinatorial synthesis of [EMIM]-based ionic liquids
    Himmler, S.
    Koenig, A.
    Wasserscheid, P.
    GREEN CHEMISTRY, 2007, 9 (09) : 935 - 942
12345