Homochiral porous metal-organic frameworks containing only achiral building blocks for enantioselective separation

被引：53
|
作者：
Zhang, Hai-Xia [1 ]
Wang, Fei [1 ]
Tan, Yan-Xi [1 ]
Kang, Yao [1 ]
Zhang, Jian [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 32期
关键词：
SINGLE-CRYSTAL TRANSFORMATIONS; COORDINATION POLYMER; REVERSIBLE ADSORPTION; NANOPOROUS MATERIALS; HYDROGEN; CRYSTALLIZATION; INDUCTION; CATALYSIS; ZEOLITE; STORAGE;
D O I：
10.1039/c2jm33269h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Enantioselective separation of racemic 1-phenethanol via hydrogen bonding interactions is realized in two enantiomorphous robust metal-organic frameworks (MOFs) with permanent porosity for high hydrogen uptake and reversible guest exchange function through a single-crystal-to-single-crystal fashion, which opens a new route toward enantioselective separation by employing low-cost homochiral MOFs containing only achiral building blocks.
引用
收藏
页码：16288 / 16292
页数：5
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