Thermoelectric properties of Ni-doped CuInTe2

被引：34

作者：

Kucek, V. ^{[1
]}

Drasar, C. ^{[1
]}

Navratil, J. ^{[2
]}

Plechacek, T. ^{[1
]}

Benes, L. ^{[1
]}

机构：

[1] Univ Pardubice, Fac Chem Technol, Pardubice 53210, Czech Republic

[2] Acad Sci Czech Republic, Inst Macromol Chem, Prague 12006, Czech Republic

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2015年 / 83卷

关键词：

Semiconductors; Chalcogenides; X-ray diffraction; Transport properties; CHALCOPYRITE; CUINSE2; EFFICIENCY; SYSTEM;

D O I：

10.1016/j.jpcs.2015.03.012

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polycrystalline samples of composition Cu1-xNixInTe2 (for x=0-0.05) were synthesized from elements of 5 N purity using a solid-state reaction. The phase purity of the products was verified by X-ray diffraction. Samples for measurement of the transport properties were prepared using hot-pressing. The samples were then characterized by the measurement of electrical conductivity, the Hall coefficient, the Seebeck coefficient, and the thermal conductivity over a temperature range of 300-675 K. All of the samples demonstrate p-type conductivity. We discuss the influence of Ni substitution on the free carrier concentration and the thermoelectric performance. The investigation of the thermoelectric properties shows an improvement up to 50% of Zr in the temperature range of 300-600 K. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：18 / 23

页数：6

共 26 条

[1]

Berger L. I., 1964, IZV AN SSSR FIZ, V28, P1100

[2] Enhanced thermoelectric performance in Cd doped CuInTe2 compounds [J].

Cheng, N. ;

Liu, R. ;

Bai, S. ;

Shi, X. ;

Chen, L. .

JOURNAL OF APPLIED PHYSICS, 2014, 115 (16)

[3] SOUND VELOCITIES AND ELASTIC-MODULI IN CUINTE2 AND CUINSE2 [J].

FERNANDEZ, B ;

WASIM, SM .

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1990, 122 (01) :235-242

[4] Enhancement of thermoelectric efficiency in PbTe by distortion of the electronic density of states [J].

Heremans, Joseph P. ;

Jovovic, Vladimir ;

Toberer, Eric S. ;

Saramat, Ali ;

Kurosaki, Ken ;

Charoenphakdee, Anek ;

Yamanaka, Shinsuke ;

Snyder, G. Jeffrey .

SCIENCE, 2008, 321 (5888) :554-557

[5] Thermoelectric properties of n-type 95%Bi2Te3-5%Bi2Se3 compounds fabricated by gas-atomization and spark plasma sintering [J].

Kim, Hyo-Seob ;

Hong, Soon-Jik .

JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 586 :S428-S431

[6] High-temperature thermoelectric properties of Cu1-xInTe2 with a chalcopyrite structure [J].

Kosuga, Atsuko ;

Plirdpring, Theerayuth ;

Higashine, Ryosuke ;

Matsuzawa, Mie ;

Kurosaki, Ken ;

Yamanaka, Shinsuke .

APPLIED PHYSICS LETTERS, 2012, 100 (04)

[7]

Lev I., 1969, DIAMOND LIKE SEMICON

[8] High thermoelectric performance of solid solutions CuGa1-xInxTe2 (x=0-1.0) [J].

Li, Yapeng ;

Meng, Qingsen ;

Deng, Yuan ;

Zhou, Hong ;

Gao, Yulan ;

Li, Yiyun ;

Yang, Jiangfeng ;

Cui, Jiaolin .

APPLIED PHYSICS LETTERS, 2012, 100 (23)

[9] Improved Thermoelectric Properties of Cu-Doped Quaternary Chalcogenides of Cu2CdSnSe4 [J].

Liu, Min-Ling ;

Chen, I-Wei ;

Huang, Fu-Qiang ;

Chen, Li-Dong .

ADVANCED MATERIALS, 2009, 21 (37) :3808-3812

[10] Ternary compound CuInTe2: a promising thermoelectric material with diamond-like structure [J].

Liu, Ruiheng ;

Xi, Lili ;

Liu, Huili ;

Shi, Xun ;

Zhang, Wenqing ;

Chen, Lidong .

CHEMICAL COMMUNICATIONS, 2012, 48 (32) :3818-3820

← 1 2 3 →