Hydrosilane and bismuth-accelerated palladium catalyzed aerobic oxidative esterification of benzylic alcohols with air

被引:53
作者
Bai, Xing-Feng [1 ]
Ye, Fei [1 ]
Zheng, Long-Sheng [1 ]
Lai, Guo-Qiao [1 ]
Xia, Chun-Gu [2 ]
Xu, Li-Wen [1 ,2 ]
机构
[1] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
基金
中国国家自然科学基金;
关键词
SUBSTITUTION-REACTIONS; ALDEHYDES;
D O I
10.1039/c2cc34117d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In a palladium- catalyzed oxidative esterification, hydrosilane can serve as an activator of palladium catalyst with bismuth, thus leading to a novel ligand- and silver-free palladium catalyst system for facile oxidative esterification of a variety of benzylic alcohols in good yields.
引用
收藏
页码:8592 / 8594
页数:3
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