TiO2 on MoSe2 nanosheets as an advanced photocatalyst for hydrogen evolution in visible light

被引:23
|
作者
Kou, Shufang [1 ]
Guo, Xia [1 ]
Xu, Xiaofeng [1 ]
Yang, Jian [1 ]
机构
[1] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
Photocatalyst; Hydrogen evolution; Visible light; MoSe2; TiO2; ELECTRONIC-STRUCTURE; SHELL; XPS; SPECTROSCOPY; WATER; WSE2;
D O I
10.1016/j.catcom.2017.12.013
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
TiO2 grown on MoSe2 nanosheets was synthesized by a simple process and explored as photocatalyst for hydrogen generation. In visible light, hydrogen generation rate over the MoSe2/TiO2 photocatalyst was found to be 468.2 mu mol h(-1) g(-1), much higher than the corresponding rates obtained over the MoSe2, TiO2 and their physical mixture. It is suggested that the good absorption of MoSe2 to visible light and the improved charge separation by the interface of MoSe2/TiO2 greatly promote hydrogen generation rate, as supported by the transient photocurrent responses and electrochemical impedance spectra recorded.
引用
收藏
页码:60 / 63
页数:4
相关论文
共 50 条
  • [1] Perpendicularly Oriented MoSe2/Graphene Nanosheets as Advanced Electrocatalysts for Hydrogen Evolution
    Mao, Shun
    Wen, Zhenhai
    Ci, Suqin
    Guo, Xiaoru
    Ostrikov, Kostya
    Chen, Junhong
    SMALL, 2015, 11 (04) : 414 - 419
  • [2] Mixed-dimensional TiO2 nanoparticles with MoSe2 nanosheets for photochemical hydrogen generation
    Yongzhen Shen
    Xiaohui Ren
    Guanghua Xu
    Zongyu Huang
    Xiang Qi
    Journal of Materials Science: Materials in Electronics, 2017, 28 : 2023 - 2028
  • [3] Mixed-dimensional TiO2 nanoparticles with MoSe2 nanosheets for photochemical hydrogen generation
    Shen, Yongzhen
    Ren, Xiaohui
    Xu, Guanghua
    Huang, Zongyu
    Qi, Xiang
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (02) : 2023 - 2028
  • [4] Ternary TiO2/MoSe2/γ-graphyne heterojunctions with enhanced photocatalytic hydrogen evolution
    Wu, Lulu
    Li, Qiaodan
    Yang, Chaofan
    Chen, Yang
    Dai, Zhaoqing
    Yao, Boyu
    Zhang, Xiaoyan
    Cui, Xiaoli
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2020, 31 (11) : 8796 - 8804
  • [5] Ternary TiO2/MoSe2/γ-graphyne heterojunctions with enhanced photocatalytic hydrogen evolution
    Lulu Wu
    Qiaodan Li
    Chaofan Yang
    Yang Chen
    Zhaoqing Dai
    Boyu Yao
    Xiaoyan Zhang
    Xiaoli Cui
    Journal of Materials Science: Materials in Electronics, 2020, 31 : 8796 - 8804
  • [6] Atomic Layer Deposition of MoSe2 Nanosheets on TiO2 Nanotube Arrays for Photocatalytic Dye Degradation and Electrocatalytic Hydrogen Evolution
    Zazpe, Raul
    Krumpolec, Richard
    Sopha, Hanna
    Rodriguez-Pereira, Jhonatan
    Charvot, Jaroslav
    Hromadko, Ludek
    Kolibalova, Eva
    Michalicka, Jan
    Pavlinak, David
    Motola, Martin
    Prikryl, Jan
    Krbal, Milos
    Bures, Filip
    Macak, Jan M.
    ACS APPLIED NANO MATERIALS, 2020, 3 (12) : 12034 - 12045
  • [7] TiOxNy/TiO2 Photocatalyst for Hydrogen Evolution under Visible-Light Irradiation. I: Characterization of N in TiOxNy/TiO2 Photocatalyst
    Ozawa, Akiyo
    Yamamoto, Muneaki
    Tanabe, Tetsuo
    Yoshida, Tomoko
    ACS OMEGA, 2019, 4 (24): : 20424 - 20429
  • [8] MoSe2 Nanosheets with Tuneable Optical Properties for Broadband Visible Light Photodetection
    Ghorai, Arup
    Ray, Samit K.
    Midya, Anupam
    ACS APPLIED NANO MATERIALS, 2021, 4 (03) : 2999 - 3006
  • [9] TiO2 nanoparticles modified with 2D MoSe2 for enhanced photocatalytic activity on hydrogen evolution
    Wu, Lulu
    Shi, Shuai
    Li, Qiaodan
    Zhang, Xiaoyan
    Cui, Xiaoli
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (02) : 720 - 728
  • [10] TiO2 @ MoSe2 line-to-face heterostructure: An advanced photocatalyst for highly efficient reduction of Cr (VI)
    Zhang, Shumin
    Chen, Liang
    Shen, Jie
    Li, Zhongfu
    Wu, Zhaohui
    Feng, Wenhui
    Xu, Kaiqiang
    Xu, Difa
    Chen, Xiaohua
    Zhang, Shiying
    CERAMICS INTERNATIONAL, 2019, 45 (14) : 18065 - 18072