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A stereoselectively deuterated supramolecular motif to probe the role of solvent during self-assembly processes
被引:48
作者:
Cantekin, Seda
[2
]
Nakano, Yoko
[2
]
Everts, Jeffrey C.
[1
,2
]
van der Schoot, Paul
[1
,3
]
Meijer, E. W.
[2
]
Palmans, Anja R. A.
[2
]
机构:
[1] Eindhoven Univ Technol, Dept Appl Phys, Grp Theory Polymers & Soft Matter, NL-5600 MB Eindhoven, Netherlands
[2] Eindhoven Univ Technol, Inst Complex Mol Syst, NL-5600 MB Eindhoven, Netherlands
[3] Univ Utrecht, Inst Theoret Fys, NL-3584 CE Utrecht, Netherlands
关键词:
HELICAL TRANSITION;
SOLDIERS PRINCIPLE;
CHIRALITY;
UREA;
POLYMER;
D O I:
10.1039/c2cc17284d
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Small changes in the alkane solvent structure in combination with temperature effects lead to four different conformations of stereoselectively deuterated benzene-1,3,5-tricarboxamides in the aggregated state, affecting the expression of the supramolecular chirality and highlighting the role of the solvent structure in self-assembly processes.
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页码:3803 / 3805
页数:3
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