A stereoselectively deuterated supramolecular motif to probe the role of solvent during self-assembly processes

被引:48
作者
Cantekin, Seda [2 ]
Nakano, Yoko [2 ]
Everts, Jeffrey C. [1 ,2 ]
van der Schoot, Paul [1 ,3 ]
Meijer, E. W. [2 ]
Palmans, Anja R. A. [2 ]
机构
[1] Eindhoven Univ Technol, Dept Appl Phys, Grp Theory Polymers & Soft Matter, NL-5600 MB Eindhoven, Netherlands
[2] Eindhoven Univ Technol, Inst Complex Mol Syst, NL-5600 MB Eindhoven, Netherlands
[3] Univ Utrecht, Inst Theoret Fys, NL-3584 CE Utrecht, Netherlands
关键词
HELICAL TRANSITION; SOLDIERS PRINCIPLE; CHIRALITY; UREA; POLYMER;
D O I
10.1039/c2cc17284d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Small changes in the alkane solvent structure in combination with temperature effects lead to four different conformations of stereoselectively deuterated benzene-1,3,5-tricarboxamides in the aggregated state, affecting the expression of the supramolecular chirality and highlighting the role of the solvent structure in self-assembly processes.
引用
收藏
页码:3803 / 3805
页数:3
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