A stereoselectively deuterated supramolecular motif to probe the role of solvent during self-assembly processes

被引：48

作者：

Cantekin, Seda ^{[2
]}

Nakano, Yoko ^{[2
]}

Everts, Jeffrey C. ^{[1
,2
]}

van der Schoot, Paul ^{[1
,3
]}

Meijer, E. W. ^{[2
]}

Palmans, Anja R. A. ^{[2
]}

机构：

[1] Eindhoven Univ Technol, Dept Appl Phys, Grp Theory Polymers & Soft Matter, NL-5600 MB Eindhoven, Netherlands

[2] Eindhoven Univ Technol, Inst Complex Mol Syst, NL-5600 MB Eindhoven, Netherlands

[3] Univ Utrecht, Inst Theoret Fys, NL-3584 CE Utrecht, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 32期

关键词：

HELICAL TRANSITION; SOLDIERS PRINCIPLE; CHIRALITY; UREA; POLYMER;

D O I：

10.1039/c2cc17284d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Small changes in the alkane solvent structure in combination with temperature effects lead to four different conformations of stereoselectively deuterated benzene-1,3,5-tricarboxamides in the aggregated state, affecting the expression of the supramolecular chirality and highlighting the role of the solvent structure in self-assembly processes.

引用

页码：3803 / 3805

页数：3

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