The Effect of Synthetic Conditions on the Characteristics of Carrageenan-Doped Poly(3,4-ethylenedioxythiophene)

被引：1

作者：

Diah, Anang W. M. ^{[1
]}

Wirayudha, Agung ^{[1
]}

Kandolia, Trisanti V. ^{[1
]}

Pujianti, Ni K. T. ^{[1
]}

Widyakirana, Iis ^{[1
]}

Hasriani, Nurul A. Safitra ^{[1
]}

Saehana, Sahrul ^{[2
]}

Holdsworth, Clovia I. ^{[3
]}

机构：

[1] Tadulako Univ, Discipline Chem, Fac Teacher Training & Educ, Palu 94118, Indonesia

[2] Tadulako Univ, Discipline Phys, Fac Teacher Training & Educ, Palu 94118, Indonesia

[3] Univ Newcastle, Sch Environm & Life Sci, Chem, Callaghan, NSW 2308, Australia

来源：

MACROMOLECULAR SYMPOSIA | 2020年 / 391卷 / 01期

关键词：

carrageenan; oxidative polymerization; poly(3; 4-ethylenedioxythiophene); processability; ELECTRICAL-CONDUCTIVITY; SPECTROSCOPY; ENHANCEMENT; SULFONIC-ACID); PERFORMANCE; PEDOT; FILMS;

D O I：

10.1002/masy.201900162

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Carrageenan-doped poly(3,4-ethylenedioxythiophene) (PEDOT) is synthesized via oxidative polymerization of 3,4-ethylenedioxythiophene monomer, using Na(2)S(2)O(8)and Fe-2(SO4)(3)as oxidation agents, at a controlled pH of 10-11, in the presence of carrageenan as the doping agent (dopant). As with polystyrene sulfonate, the most common doping agent for PEDOT, carrageenan also possess -SO3 (-)functional groups that are capable of interacting with PEDOT chains. The PEDOT/carrageenan (PEDOT/Carr) dispersions are prepared in this study in 1:1, 1:2, and 1:4 ratios by weight. Different types of carrageenans result in PEDOT/Carr dispersions of different processabilities. The PEDOT/Carr ratios are investigated for their effects on the physical properties of the films. The results show that carrageenan is successfully doped to PEDOT to form PEDOT/Carr complex. Increasing amount of carrageenan in dispersion result in more processable PEDOT/Carr dispersions.

引用

页数：5