Imidazolium-based chiral ionic liquids: synthesis and application

被引：26
|
作者：
Suzuki, Yumiko [1 ]
Wakatsuki, Junichiro [2 ]
Tsubaki, Mariko [2 ]
Sato, Masayuki [2 ]
机构：
[1] Sophia Univ, Fac Sci & Technol, Dept Mat & Life Sci, Chiyoda Ku, Tokyo 1028554, Japan
[2] Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, Shizuoka 4228526, Japan
来源：
TETRAHEDRON | 2013年 / 69卷 / 46期
关键词：
Chiral ionic liquid; Chiral solvent; Imidazolium salt; Michael addition; MICHAEL ADDITION; SOLVENTS;
D O I：
10.1016/j.tet.2013.09.017
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Synthesis of chiral ionic liquids containing an imidazole nucleus and chiral centers on N-substituents is reported. [(2S,3S)-2,3-Dihydroxybutane-1,4-bis(3-butylimidazolium)]-[bis(trifluoromethanesulfonyl)amide](2) and [(4S,5S)-2-phenyl-1,3-dioxolane-4,5-bis(1-methylimidazolium)]-[bis(trifluoromethanesulfonyl)amide](2) induced enantioselectivity in the Michael addition of malonic esters to chalcones. (c) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：9690 / 9700
页数：11
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