A concise synthesis of (+)-pancratistatin using pinitol as a chiral building block

被引：53

作者：

Li, Min

Wu, Anmei

Zhou, Peijie

机构：

[1] Georgetown Univ, Med Ctr, Dept Neurosci, Washington, DC 20057 USA

[2] Orgchem Technol Inc, Chicago, IL 60612 USA

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 22期

关键词：

pancratistatin; stereoselective synthesis; pinitol; cyclic sulfate; arylcerium;

D O I：

10.1016/j.tetlet.2006.03.138

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A concise approach toward (+)-Pancratistatin has been achieved via 12 steps from pinitol. An ultrasound assisted arylcerium induced ring opening of cyclic sulfate was employed as a key step. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：3707 / 3710

页数：4

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