Two Manganese(II) Supramolecular Complexes Based on Imidazole Dicarboxylates: Syntheses, Crystal Structures, and Properties

被引：3

作者：

Li, Jie ^{[1
]}

Guo, Beibei ^{[1
]}

Liu, Shaofeng ^{[1
]}

Li, Gang ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2014年 / 44卷 / 07期

基金：

中国国家自然科学基金;

关键词：

property; Mn(II); crystal structure; synthesis; supramolecule; GAS-ADSORPTION; CONSTRUCTION; MOFS; SERIES; ZN;

D O I：

10.1080/15533174.2013.797463

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel Mn(II) complexes [Mn(MDPhH2IDC)(2)(H2O)(2)] (n) (1) (MDPhH3IDC = 2-(3,4-methylenedioxyphenyl)-1H-imidazole-4, 5-dicarboxylic acid), [Mn( m-CPhH3IDC)(2)(H2O)(2)] (n) (2) (m-CPh H4IDC = 2-(3-carboxylphenyl)-1H-imidazole-4,5-dicarboxylic acid) have been hydrothermally synthesized with two kinds of imidazole dicarboxylate ligands, respectively, and structurally characterized by elemental analyses, IR spectra, as well as single crystal X-ray diffraction analysis. The 3D solid-state supramolecular structures of the complexes involve intermolecular hydrogen bonds. Furthermore, the thermal and photoluminescent properties of the complexes have been investigated.

引用

页码：1041 / 1049

页数：9

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