A Novel Supramolecular Tetrahedron Assembled from Tetranuclear Copper(I) Cluster Molecules via Aryl Embrace Interactions

被引：65

作者：

Wei, Wei ^{[1
,2
]}

Wu, Mingyan ^{[1
]}

Gao, Qiang ^{[1
,2
]}

Zhang, Qingfu ^{[1
,2
]}

Huang, Yougui ^{[1
]}

Jiang, Feilong ^{[1
]}

Hong, Maochun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 02期

关键词：

METAL-COMPLEXES; ELECTROCHEMICAL SYNTHESIS; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; CONSTRUCTION; NETWORKS; CLEAVAGE; LIGANDS; BINDING; MOTIFS;

D O I：

10.1021/ic801972e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An intriguing supramolecular tetrahedral aggregate [Cu4I(ptt)(3)(Hptt)(3)](4) (1; Hptt = 1-phenyl-1H-tetrazole-5-thiol) based on novel copper(I) iodide thiolate clusters in the solid state has been synthesized and characterized. Four tetra-copper(I) cluster molecules join together with the cooperation of multiple offset face-to-face pi-pi stacking (OFF) and edge-to-face C-H center dot center dot center dot pi (EF) interactions in the form of aryl embrace of a (EF)(3)(OFF)(3) motif, which leads to the formation of this tetrahedral aggregate. Furthermore, this complex exhibits a temperature-dependent green photoluminescence.

引用

页码：420 / 422

页数：3

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