Glass alteration in atmospheric conditions: crossing perspectives from cultural heritage, glass industry, and nuclear waste management

被引:50
作者
Majerus, Odile [1 ]
Lehuede, Patrice [2 ]
Biron, Isabelle [2 ]
Alloteau, Fanny [1 ,2 ]
Narayanasamy, Sathya [3 ]
Caurant, Daniel [1 ]
机构
[1] PSL Univ, Chim ParisTech, CNRS, Inst Rech Chim Paris IRCP, F-75005 Paris, France
[2] Ctr Rech & Restaurat Musees France C2RMF, F-75001 Paris, France
[3] CEA Marcoule, DEN, MAR, DE2D,SEVT LCLT, F-30207 Bagnols Sur Ceze, France
关键词
BOROSILICATE GLASSES; CHEMICAL DURABILITY; VAPOR HYDRATION; SURFACE ALTERATION; AQUEOUS CORROSION; SILICATE-GLASSES; OXIDE GLASSES; SON68; GLASS; DEGREES-C; STATE;
D O I
10.1038/s41529-020-00130-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
While glass alteration in liquid water has been widely studied for decades, glass alteration in unsaturated atmosphere (relative humidity, RH < 100%) has been far less examined. However, the understanding of the mechanisms involved in the reactions between glass and water in vapor state is fundamental to several fields such as glass industry, conservation of glasses of the cultural heritage and long-term assessment of nuclear waste glasses. This paper outlines the issues raised by the atmospheric alteration of glass in these fields and attempts to summarize the scientific approaches and findings of the three communities. This short review reveals that atmospheric alteration should not be confused with liquid alteration at highS/V(S = exposed surface of glass andV = volume of solution), because the kinetics and the nature of the alteration products are distinct. Notably, alkalies and non-bridging oxygens may be significantly retained in glass hydrated in unsaturated atmosphere, depending on the glass composition. Future lines of research are drawn to progress in the understanding of the specificities of atmospheric glass alteration.
引用
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页数:16
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