Carbene-stabilized main group radicals and radical ions

被引：392

作者：

Martin, Caleb D. ^{[1
]}

Soleilhavoup, Michele ^{[1
]}

Bertrand, Guy ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, Joint CNRS UCSD Res Lab UMI 3555, La Jolla, CA 92093 USA

来源：

CHEMICAL SCIENCE | 2013年 / 4卷 / 08期

关键词：

N-HETEROCYCLIC CARBENE; ELECTRON-PARAMAGNETIC-RESONANCE; TRANSITION-METAL-COMPLEXES; PINCER DICARBENE COMPLEXES; ALKYL AMINO CARBENES; PHOSPHORUS-CONTAINING RADICALS; STABLE NUCLEOPHILIC CARBENE; BORON TRIPLE BOND; IN-THE-BOX; PI-ACCEPTOR;

D O I：

10.1039/c3sc51174j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Shortly after their discovery at the end of the 80s, stable singlet carbenes have been recognized as excellent ligands for transition metal based catalysts, and as organo-catalysts in their own right. At the end of the 2000s, it has been shown that they can coordinate main group elements in their zero oxidation state, and even activate small molecules. This review covers examples in the literature dealing with the most recent application of stable singlet carbenes, namely their use to stabilize radicals and radical ions that are otherwise unstable.

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页码：3020 / 3030

页数：11

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