Tetracoordinate Imidazole-Based Boron Complexes for the Selective Detection of Picric Acid

被引：47

作者：

Dhanunjayarao, Kunchala ^{[1
]}

Mukundam, Vanga ^{[1
]}

Venkatasubbaiah, Krishnan ^{[1
]}

机构：

[1] Natl Inst Sci Educ & Res, Sch Chem Sci, Bhubaneswar 752050, Orissa, India

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 21期

关键词：

METAL-ORGANIC FRAMEWORK; AGGREGATION-INDUCED EMISSION; PI-ELECTRON MATERIALS; NITROAROMATIC EXPLOSIVES; ORGANOBORON COMPOUNDS; EFFICIENT DETECTION; AQUEOUS-MEDIA; SOLID SUPPORT; POLYMERS; STATE;

D O I：

10.1021/acs.inorgchem.6b01767

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N,N-Dimethylamine and N,N-diphenylaminedecorated highly fluorescent imidazole borates have been synthesized and investigated as new fluorophores for the selective detection of trinitrophenol/picric acid (PA). Structural studies of a probe 1 and PA (1.PPM) complex revealed that the adduct formed by the deprotonation of PA by the -NMe2 group along with weak interactions is responsible for the selective detection of PA over other polynitrated organic compounds.

引用

页码：11153 / 11159

页数：7

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