Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2-(α-SbW9O33)6]27- based on abundant metals

被引：86

作者：

Du, Xiaoqiang ^{[1
,2
]}

Ding, Yong ^{[1
,2
,3
]}

Song, Fangyuan ^{[1
,2
]}

Ma, Baochun ^{[1
,2
]}

Zhao, Junwei ^{[4
]}

Song, Jie ^{[5
,6
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Peoples R China

[2] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China

[3] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

[4] Henan Univ, Coll Chem & Chem Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng 475004, Henan, Peoples R China

[5] Emory Univ, Dept Biomed Engn, Atlanta, GA 30322 USA

[6] Georgia Inst Technol, Atlanta, GA 30322 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 73期

基金：

中国国家自然科学基金;

关键词：

IRON; COMPLEXES; COPPER;

D O I：

10.1039/c5cc04551g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An eleven iron-containing nanoscale inorganic polyanionic oxide cluster was reported as the first example for exceptional photocatalytic water oxidation. Under optimal conditions, a remarkable turn-over number (TON) of 1815 +/- 50 and a turn-over frequency (TOFinitial) of 6.3 s(-1) over 1 were achieved for water oxidation.

引用

收藏

页码：13925 / 13928

页数：4

相关论文

共 32 条

[21] A cobalt(II) quaterpyridine complex as a visible light-driven catalyst for both water oxidation and reduction [J].

Leung, Chi-Fai ;

Ng, Siu-Mui ;

Ko, Chi-Chiu ;

Man, Wai-Lun ;

Wu, Jiashou ;

Chen, Lingjing ;

Lau, Tai-Chu .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (07) :7903-7907

[22] An Exceptionally Fast Homogeneous Carbon-Free Cobalt-Based Water Oxidation Catalyst [J].

Lv, Hongjin ;

Song, Jie ;

Geletii, Yurii V. ;

Vickers, James W. ;

Sumliner, Jordan M. ;

Musaev, Djamaladdin G. ;

Koegerler, Paul ;

Zhuk, Petro F. ;

Bacsa, John ;

Zhu, Guibo ;

Hill, Craig L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (26) :9268-9271

[23] A Co4O4 "Cubane" Water Oxidation Catalyst Inspired by Photosynthesis [J].

McCool, Nicholas S. ;

Robinson, David M. ;

Sheats, John E. ;

Dismukes, G. Charles .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (30) :11446-11449

[24] K7[CoIIICoII(H2O)W11O39]: a molecular mixed-valence Keggin polyoxometalate catalyst of high stability and efficiency for visible light-driven water oxidation [J].

Song, Fangyuan ;

Ding, Yong ;

Ma, Baochun ;

Wang, Changming ;

Wang, Qiang ;

Du, Xiaoqiang ;

Fua, Shao ;

Song, Jie .

ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (04) :1170-1184

[25] Recent advances on polyoxometalate-based molecular and composite materials [J].

Song, Yu-Fei ;

Tsunashima, Ryo .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (22) :7384-7402

[26] Visible light-induced water oxidation catalyzed by molybdenum-based polyoxometalates with mono- and dicobalt(III) cores as oxygen-evolving centers [J].

Tanaka, Saya ;

Annaka, Masahiko ;

Sakai, Ken .

CHEMICAL COMMUNICATIONS, 2012, 48 (11) :1653-1655

[27]

Vigara L., 2012, INORG CHEM, V51, P11707

[28] Recent Advances in Polyoxometalate-Catalyzed Reactions [J].

Wang, Sa-Sa ;

Yang, Guo-Yu .

CHEMICAL REVIEWS, 2015, 115 (11) :4893-4962

[29] A Bioinspired Molecular Polyoxometalate Catalyst with Two Cobalt(II) Oxide Cores for Photocatalytic Water Oxidation [J].

Wei, Jie ;

Feng, Yingying ;

Zhou, Panpan ;

Liu, Yan ;

Xu, Jingyin ;

Xiang, Rui ;

Ding, Yong ;

Zhao, Chongchao ;

Fan, Linyuan ;

Hu, Changwen .

CHEMSUSCHEM, 2015, 8 (16) :2630-2634

[30] Visible-Light-Induced Water Oxidation Mediated by a Mononuclear-Cobalt(II)-Substituted Silicotungstate [J].

Xiang, Rui ;

Ding, Yong ;

Zhao, Junwei .

CHEMISTRY-AN ASIAN JOURNAL, 2014, 9 (11) :3228-3237

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