Luminescence properties of B2O3-GeO2-Gd2O3 scintillating glass doped with rare-earth and transition-metal ions

被引:37
作者
Sun, Xin-Yuan [1 ]
Jiang, Da-Guo [1 ]
Wang, Wen-Feng [1 ]
Cao, Chun-Yan [1 ]
Li, Yu-Nong [1 ]
Zhen, Guo-Tai [1 ]
Wang, Hong [2 ]
Yang, Xin-Xin [2 ]
Chen, Hao-Hong [2 ]
Zhang, Zhi-Jun [2 ]
Zhao, Jing-Tai [2 ]
机构
[1] Jinggangshan Univ, Dept Phys, Jian 343009, Jiangxi, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Transparent Optofunct Inorgan Mat, Shanghai 200050, Peoples R China
关键词
B2O3-GeO2-Gd2O3 ternary system; Borogermanate scintillating glass; Photoluminescence; X-ray excited luminescence; Energy transfer; OPTICAL-PROPERTIES; ENERGY-TRANSFER; PHOTOLUMINESCENCE; RADIOLUMINESCENCE; GERMANATE;
D O I
10.1016/j.nima.2013.03.036
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Novel B2O3-GeO2-Gd2O3 ternary scintillating glasses doped with 1 mol% rare-earth and transition-metal activators were synthesized by melt-quenching method. Their transmittance, photoluminescence (PL) and X-ray excited luminescence (XEL) spectra were investigated. The results suggest that a high content of Gd2O3 is of significance for designing dense glass with density of 6.0 g/cm(3). And energy transfer from Gd3+ to the incorporated activators can be realized in the borogermanate glasses. The emission position and decay time can be efficiently tuned by incorporating various kinds of activators. All results imply the developed borogermanate scintillating glass is potential for scintillating fields. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:90 / 95
页数:6
相关论文
共 32 条
  • [1] Evaluation of a high-density scintillating glass for portal imaging
    Bissonnette, JP
    Munro, P
    [J]. MEDICAL PHYSICS, 1996, 23 (03) : 401 - 406
  • [2] BUCHANAN RA, 1995, Patent No. 5391320
  • [3] BUENO C, 1990, P SOC PHOTO-OPT INS, V1327, P79, DOI 10.1117/12.22521
  • [4] Color-tunable luminescence of Eu3+ in LaF3 embedded nanocomposite for light emitting diode
    Chen, Daqin
    Yu, Yunlong
    Huang, Ping
    Lin, Hang
    Shan, Zhifa
    Wang, Yuansheng
    [J]. ACTA MATERIALIA, 2010, 58 (08) : 3035 - 3041
  • [5] Chen GR, 2005, J AM CERAM SOC, V88, P293, DOI [10.1111/j.1551.1926.2005.00075.x, 10.1111/j.1551-2916.2005.00075.x]
  • [6] Luminescence and scintillation of Ce3+-doped oxide glass with high Gd2O3 concentration
    Chewpraditkul, W.
    He, X.
    Chen, D.
    Shen, Y.
    Sheng, Q.
    Yu, B.
    Nikl, M.
    Kucerkova, R.
    Beitlerova, A.
    Wanarak, C.
    Phunpueok, A.
    [J]. PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2011, 208 (12): : 2830 - 2832
  • [7] Intense red photoluminescence from Mn2+-doped (Na+; Zn2+) sulfophosphate glasses and glass ceramics as LED converters
    Da, Ning
    Peng, Mingying
    Krolikowski, Sebastian
    Wondraczek, Lothar
    [J]. OPTICS EXPRESS, 2010, 18 (03): : 2549 - 2557
  • [8] HEAVY-METAL OXIDE GLASSES
    DUMBAUGH, WH
    LAPP, JC
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1992, 75 (09) : 2315 - 2326
  • [9] Eu3+-activated heavy scintillating glasses
    Fu, J.
    Kobayashi, A.
    Sugimoto, S.
    Parker, J. M.
    [J]. MATERIALS RESEARCH BULLETIN, 2008, 43 (06) : 1502 - 1508
  • [10] Compositional dependence of scintillation yield of glasses with high Gd2O3 concentrations
    Fu, J
    Parker, JM
    Brown, RM
    Flower, PS
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2003, 326 : 335 - 338