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Hierarchical Self-Assembly of Edge-On Nanocolumnar Superstructures of Large Disc-Like Molecules
被引:43
|作者:
Piot, Luc
[2
,3
]
Marie, Camille
[2
,3
]
Feng, Xinliang
[1
]
Muellen, Klaus
[1
]
Fichou, Denis
[2
,3
]
机构:
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] CEA Saclay, SPCSI, IRAMIS, LRC Nanostruct & Semicond Organ, F-91191 Gif Sur Yvette, France
[3] Univ Paris 06, CNRS, UMR 7611, F-75252 Paris, France
关键词:
D O I:
10.1002/adma.200801428
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Long uniaxial edge-on nanocolumnar stacks of dodecyl-substituted hexa-peri-hexabenzocoronene grow spontaneously at the liquid/solid interface as a result of a hierarchical self-assembly process. Supramolecular multilayered architectures as complex as {HOPG/face-on/edge-on/edge-on} and {HOPG/face-on/edge-on/face-on} are produced, paving the way towards future applications in organic nanodevices. [GRAPHICS]
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页码:3854 / +
页数:6
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