Hierarchical Self-Assembly of Edge-On Nanocolumnar Superstructures of Large Disc-Like Molecules

被引:43
|
作者
Piot, Luc [2 ,3 ]
Marie, Camille [2 ,3 ]
Feng, Xinliang [1 ]
Muellen, Klaus [1 ]
Fichou, Denis [2 ,3 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] CEA Saclay, SPCSI, IRAMIS, LRC Nanostruct & Semicond Organ, F-91191 Gif Sur Yvette, France
[3] Univ Paris 06, CNRS, UMR 7611, F-75252 Paris, France
关键词
D O I
10.1002/adma.200801428
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Long uniaxial edge-on nanocolumnar stacks of dodecyl-substituted hexa-peri-hexabenzocoronene grow spontaneously at the liquid/solid interface as a result of a hierarchical self-assembly process. Supramolecular multilayered architectures as complex as {HOPG/face-on/edge-on/edge-on} and {HOPG/face-on/edge-on/face-on} are produced, paving the way towards future applications in organic nanodevices. [GRAPHICS]
引用
收藏
页码:3854 / +
页数:6
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