Electrocatalytic and Photocatalytic Hydrogen Production in Aqueous Solution by a Molecular Cobalt Complex

被引：276

作者：

Singh, Wangkheimayum Marjit ^{[1
]}

Baine, Teera ^{[1
]}

Kudo, Shotaro ^{[1
]}

Tian, Shiliang ^{[2
,3
]}

Ma, Xuan Anh N. ^{[1
]}

Zhou, Hongyu ^{[2
]}

DeYonker, Nathan J. ^{[1
]}

Truc Chi Pham ^{[1
]}

Bollinger, John C. ^{[2
]}

Baker, Daniel L. ^{[1
]}

Yan, Bing ^{[2
]}

Webster, Charles Edwin ^{[1
]}

Zhao, Xuan ^{[1
]}

机构：

[1] Memphis State Univ, Dept Chem, Memphis, TN 38152 USA

[2] St Jude Childrens Res Hosp, Dept Chem Biol & Therapeut, Memphis, TN 38105 USA

[3] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 24期

基金：

美国国家科学基金会;

关键词：

cobalt; electrocatalysis; homogeneous catalysis; hydrogen; photochemistry; H-2; PRODUCTION; GENERATING HYDROGEN; FUNCTIONAL MODELS; WATER REDUCTION; VISIBLE-LIGHT; ACTIVE-SITE; EVOLUTION; CATALYSTS; SYSTEM; COBALOXIMES;

D O I：

10.1002/anie.201200082

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mononuclear cobalt complex supported by a new type of pentadentate ligand catalyzed the evolution of hydrogen in purely aqueous solution (see picture). This cobalt complex could serve as both electrocatalyst and photocatalyst for efficient evolution of hydrogen. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5941 / 5944

页数：4

共 50 条

[31] Modification of eosin Y and cobalt molecular catalyst system with reduced graphene oxide for enhanced photocatalytic hydrogen production [J].

Lewandowska-Andralojc, Anna ;

Matolepszy, Artur ;

Stritt, Anika ;

Grohmann, Andreas .

CATALYSIS SCIENCE & TECHNOLOGY, 2020, 10 (14) :4693-4702

[32] A Highly Efficient Photocatalytic System for Hydrogen Production by a Robust Hydrogenase Mimic in an Aqueous Solution [J].

Wang, Feng ;

Wang, Wen-Guang ;

Wang, Xiao-Jun ;

Wang, Hong-Yan ;

Tung, Chen-Ho ;

Wu, Li-Zhu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (14) :3193-3197

[33] Hydrogen production in a neutral aqueous solution with a water-soluble copper complex [J].

Xin, Zhi-Juan ;

Liu, Si ;

Li, Cheng-Bo ;

Lei, You-Jia ;

Xue, Dong-Xu ;

Gao, Xue-Wang ;

Wang, Hong-Yan .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (07) :4202-4207

[34] A Systematic Comparative Study of Hydrogen-Evolving Molecular Catalysts in Aqueous Solutions [J].

Roy, Souvik ;

Bacchi, Marine ;

Berggren, Gustav ;

Artero, Vincent .

CHEMSUSCHEM, 2015, 8 (21) :3632-3638

[35] Structure-Functional Analysis of Hydrogen Production Catalyzed by Molecular Cobalt Complexes with Pentadentate Ligands in Aqueous Solutions [J].

Wang, Ping ;

Liang, Guangchao ;

Webster, Charles Edwin ;

Zhao, Xuan .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 2020 (37) :3534-3547

[36] Catalytic Generation of Hydrogen with Titanium Citrate and a Macrocyclic Cobalt Complex [J].

Szajna-Fuller, Ewa ;

Bakac, Andreja .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (17) :2488-2494

[37] Thermochemical and Mechanistic Studies of Electrocatalytic Hydrogen Production by Cobalt Complexes Containing Pendant Amines [J].

Wiedner, Eric S. ;

Appel, Aaron M. ;

DuBois, Daniel L. ;

Bullock, R. Morris .

INORGANIC CHEMISTRY, 2013, 52 (24) :14391-14403

[38] Research progress on 5-hydroxymethylfurfural electrocatalytic or photocatalytic oxidation coupling with hydrogen production [J].

Wang, Yao ;

Chen, Hong ;

Tang, Yongqi ;

Li, Yongdan .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2025, 104 :162-183

[39] Progress and Opportunities in Photocatalytic, Electrocatalytic, and Photoelectrocatalytic Production of Hydrogen Peroxide Coupled with Biomass Valorization [J].

Zheng, Yanmei ;

Zhang, Yinghua ;

Liang, Xiaoli ;

Ouyang, Jianghong ;

Guo, Xinli ;

Chen, Zupeng .

CHEMSUSCHEM, 2024, 17 (19)

[40] A Molecular Copper Catalyst for Electrochemical Water Reduction with a Large Hydrogen-Generation Rate Constant in Aqueous Solution [J].

Zhang, Peili ;

Wang, Mei ;

Yang, Yong ;

Yao, Tianyi ;

Sun, Licheng .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (50) :13803-13807

← 1 2 3 4 5 →