AgOTf catalyzed hydration of terminal alkynes

被引:44
作者
Das, Rima [1 ]
Chakraborty, Debashis [1 ]
机构
[1] Indian Inst Technol Madras, Dept Chem, Madras 600036, Tamil Nadu, India
关键词
hydration; alkyne; AgOTf; markovnikov addition; EtOAc; ANTI-MARKOVNIKOV HYDRATION; ACETYLENIC-COMPOUNDS; COMPLEXES; ALDEHYDES; ACID; CHLORIDE; LIGAND; SILVER; METAL; SALTS;
D O I
10.1002/aoc.2918
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The silver catalysis towards the hydration of terminal alkynes is explored using Silver(I) triflate (AgOTf). The reaction leads to the formation of only Markovnikov addition product with excellent yield. Copyright (C) 2012 John Wiley & Sons, Ltd.
引用
收藏
页码:722 / 726
页数:5
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