Synthetic metals: a novel role for organic polymers

被引:139
作者
MacDiarmid, Alan G. [1 ]
机构
[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA
关键词
Conducting polymers; Polyacetylene; Polyaniline; Nanofibers; Displays;
D O I
10.1016/S1567-1739(01)00051-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Since the initial discovery in 1977, that polyacetylene (CH), now commonly known as the prototype conducting polymer, could be p- or n-doped either chemically or electronically to the metallic state, the development of the field conducting polymers, "synthetic metals", has continued to accelerate at an unexpectedly rapid rate and a variety of other conducting polymers and their derivatives have been discovered. Potential new science/technology has been developed by combining the now well established field of electronic polymers (intrinsically conducting polymers "synthetic metals", when doped) with the emerging field of nanoscience (one dimension <100 nm). A simple and inexpensive method is described for producing conducting patterns of electronic polymers on plastic and paper from computer-designed patterns. This method, "Line Patterning", does not involve printing of the conducting polymers. The difference in hydrophobicity/hydrophilicity between a substrate and a line of regular toner printed on it by a non-modified, standard ofiice laser printer results in conducting polymer areas separated by insulating toner lines. (C) 2001 The Nobel Foundation. Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:269 / 279
页数:11
相关论文
共 43 条
  • [1] [Anonymous], 1986, Handbook of Conducting Polymers
  • [2] [Anonymous], 1997, HDB ORGANIC CONDUCTI
  • [3] [Anonymous], 1999, NAN REV MAK VIS R D
  • [4] [Anonymous], LICR E7 NOA 65 OPT A
  • [5] [Anonymous], 1986, Handbook of Conducting Polymers
  • [6] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS
    BURROUGHES, JH
    BRADLEY, DDC
    BROWN, AR
    MARKS, RN
    MACKAY, K
    FRIEND, RH
    BURN, PL
    HOLMES, AB
    [J]. NATURE, 1990, 347 (6293) : 539 - 541
  • [7] NEW SEMICONDUCTOR-DEVICE PHYSICS IN POLYMER DIODES AND TRANSISTORS
    BURROUGHES, JH
    JONES, CA
    FRIEND, RH
    [J]. NATURE, 1988, 335 (6186) : 137 - 141
  • [8] ELECTRICAL-CONDUCTIVITY IN DOPED POLYACETYLENE
    CHIANG, CK
    FINCHER, CR
    PARK, YW
    HEEGER, AJ
    SHIRAKAWA, H
    LOUIS, EJ
    GAU, SC
    MACDIARMID, AG
    [J]. PHYSICAL REVIEW LETTERS, 1977, 39 (17) : 1098 - 1101
  • [9] SYNTHESIS OF HIGHLY CONDUCTING FILMS OF DERIVATIVES OF POLYACETYLENE, (CH)X
    CHIANG, CK
    DRUY, MA
    GAU, SC
    HEEGER, AJ
    LOUIS, EJ
    MACDIARMID, AG
    PARK, YW
    SHIRAKAWA, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (03) : 1013 - 1015
  • [10] POLYANILINE - PROTONIC ACID DOPING OF THE EMERALDINE FORM TO THE METALLIC REGIME
    CHIANG, JC
    MACDIARMID, AG
    [J]. SYNTHETIC METALS, 1986, 13 (1-3) : 193 - 205