Synthetic metals: a novel role for organic polymers

被引:143
作者
MacDiarmid, Alan G. [1 ]
机构
[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA
关键词
Conducting polymers; Polyacetylene; Polyaniline; Nanofibers; Displays;
D O I
10.1016/S1567-1739(01)00051-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Since the initial discovery in 1977, that polyacetylene (CH), now commonly known as the prototype conducting polymer, could be p- or n-doped either chemically or electronically to the metallic state, the development of the field conducting polymers, "synthetic metals", has continued to accelerate at an unexpectedly rapid rate and a variety of other conducting polymers and their derivatives have been discovered. Potential new science/technology has been developed by combining the now well established field of electronic polymers (intrinsically conducting polymers "synthetic metals", when doped) with the emerging field of nanoscience (one dimension <100 nm). A simple and inexpensive method is described for producing conducting patterns of electronic polymers on plastic and paper from computer-designed patterns. This method, "Line Patterning", does not involve printing of the conducting polymers. The difference in hydrophobicity/hydrophilicity between a substrate and a line of regular toner printed on it by a non-modified, standard ofiice laser printer results in conducting polymer areas separated by insulating toner lines. (C) 2001 The Nobel Foundation. Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:269 / 279
页数:11
相关论文
共 43 条
[1]  
[Anonymous], 1986, Handbook of Conducting Polymers
[2]  
[Anonymous], 1997, HDB ORGANIC CONDUCTI
[3]  
[Anonymous], 1999, NAN REV MAK VIS R D
[4]  
[Anonymous], LICR E7 NOA 65 OPT A
[5]  
[Anonymous], 1986, Handbook of Conducting Polymers
[6]   LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].
BURROUGHES, JH ;
BRADLEY, DDC ;
BROWN, AR ;
MARKS, RN ;
MACKAY, K ;
FRIEND, RH ;
BURN, PL ;
HOLMES, AB .
NATURE, 1990, 347 (6293) :539-541
[7]   NEW SEMICONDUCTOR-DEVICE PHYSICS IN POLYMER DIODES AND TRANSISTORS [J].
BURROUGHES, JH ;
JONES, CA ;
FRIEND, RH .
NATURE, 1988, 335 (6186) :137-141
[8]   ELECTRICAL-CONDUCTIVITY IN DOPED POLYACETYLENE [J].
CHIANG, CK ;
FINCHER, CR ;
PARK, YW ;
HEEGER, AJ ;
SHIRAKAWA, H ;
LOUIS, EJ ;
GAU, SC ;
MACDIARMID, AG .
PHYSICAL REVIEW LETTERS, 1977, 39 (17) :1098-1101
[9]   SYNTHESIS OF HIGHLY CONDUCTING FILMS OF DERIVATIVES OF POLYACETYLENE, (CH)X [J].
CHIANG, CK ;
DRUY, MA ;
GAU, SC ;
HEEGER, AJ ;
LOUIS, EJ ;
MACDIARMID, AG ;
PARK, YW ;
SHIRAKAWA, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (03) :1013-1015
[10]   POLYANILINE - PROTONIC ACID DOPING OF THE EMERALDINE FORM TO THE METALLIC REGIME [J].
CHIANG, JC ;
MACDIARMID, AG .
SYNTHETIC METALS, 1986, 13 (1-3) :193-205