Ammonia line lists from 1650 to 4000 cm-1

被引:24
|
作者
Hargreaves, Robert J. [1 ]
Li, Gang [1 ]
Bernath, Peter F. [1 ,2 ]
机构
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
[2] Old Dominion Univ, Dept Chem & Biochem, Norfolk, VA 23529 USA
关键词
Emission spectra; Molecules (ammonia); Stars; (cool; low mass); Brown dwarfs; Atmospheric models; Line lists; INTERNAL PARTITION SUMS; SPECTRAL TYPE-L; ROVIBRATIONAL SPECTRA; VIBRATIONAL SYSTEM; INFRARED-SPECTRUM; BROWN DWARFS; (NH3)-N-14; INTENSITIES; NH3; ASSIGNMENTS;
D O I
10.1016/j.jqsrt.2012.02.033
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We present further line lists of ammonia (NH3) at high temperatures obtained by recording Fourier transform infrared emission spectra. Calibrated line lists are presented for 12 temperatures (300-1400 degrees C in 100 degrees C intervals) and each line list covers the 1650-4000 cm(-1) range, which includes the nu(1) and nu(3) fundamental modes (3 mu m) plus a number of combination, overtone and hot bands. Using our NH3 spectra, we have estimated empirical lower state energies (E-Low in cm(-1)) and our values have been incorporated into the line lists along with line positions ((nu) over bar in cm(-1)) and calibrated line intensities (S' in cm/molecule). We expect our hot NH3 line lists to find direct application in the modeling of planetary atmospheres and brown dwarfs. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:670 / 679
页数:10
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