Semiliquid electrolytes with anion-adsorbing metal-organic frameworks for high-rate lithium batteries

被引：10

作者：

Shen, Li ^{[1
]}

Li, Xinru ^{[1
]}

Lu, Xing ^{[1
]}

Kong, Dejia ^{[1
]}

Fortini, Alexis ^{[1
]}

Zhang, Chen ^{[1
]}

Lu, Yunfeng ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biomol Engn, 420 Westwood Plaza, Los Angeles, CA 90095 USA

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 88期

关键词：

CONDUCTIVITY; BEHAVIOR; UIO-66;

D O I：

10.1039/d0cc04232c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Adding particles of metal-organic frameworks (MOFs) into liquid electrolytes leads to semiliquid electrolytes, where nanoporous MOFs enclose anions while facilitating lithium-ion conduction. The improved transport efficiency of lithium-ions in semiliquid electrolytes boosts effective reaction kinetics, mitigates polarization, and produces affinitive electrolyte-electrode interfaces, which afford enhanced cycle durability for high-rate lithium batteries.

引用

页码：13603 / 13606

页数：4

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