REE Recovery from End-of-Life NdFeB Permanent Magnet Scrap: A Critical Review

被引:407
作者
Yang, Yongxiang [1 ]
Walton, Allan [2 ]
Sheridan, Richard [2 ]
Gueth, Konrad [3 ]
Gauss, Roland [3 ]
Gutfleisch, Oliver [4 ]
Buchert, Matthias [5 ]
Steenari, Britt-Marie [6 ]
Van Gerven, Tom [7 ]
Jones, Peter Tom [8 ]
Binnemans, Koen [9 ]
机构
[1] Delft Univ Technol, Dept Mat Sci & Engn, Mekelweg 2, NL-2628 CD Delft, Netherlands
[2] Univ Birmingham, Sch Met & Mat, Birmingham B15 2TT, W Midlands, England
[3] Project Grp IWKS, Fraunhofer ISC, Rodenbacher Chaussee 4, D-63457 Hanau, Germany
[4] Tech Univ Darmstadt, Inst Mat Sci, Alarich Weiss Str 16, D-64287 Darmstadt, Germany
[5] Oko Inst eV, Resources & Transport Div, Rheinstr 95, D-64295 Darmstadt, Germany
[6] Chalmers Univ Technol, Dept Chem & Chem Engn, S-41296 Gothenburg, Sweden
[7] Katholieke Univ Leuven, Dept Chem Engn, Celestijnenlaan 200F,Box 2424, B-3001 Leuven, Belgium
[8] Katholieke Univ Leuven, Dept Mat Engn, Kasteelpk Arenberg 44,Box 2450, B-3001 Leuven, Belgium
[9] Katholieke Univ Leuven, Dept Chem, Celestijnenlaan 200F,Box 2404, B-3001 Leuven, Belgium
关键词
Critical raw materials; Neodymium; Rare earths; Rare-earth magnets; Recycling; Urban mining; ND-FE-B; RARE-EARTH-ELEMENTS; SOLVENT-EXTRACTION; IONIC LIQUIDS; SINTERED MAGNETS; SELECTIVE EXTRACTION; ANISOTROPIC POWDER; CHLORIDE SOLUTION; CYANEX; 272; SEPARATION;
D O I
10.1007/s40831-016-0090-4
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
NdFeB permanent magnets have different life cycles, depending on the applications: from as short as 2-3 years in consumer electronics to 20-30 years in wind turbines. The size of the magnets ranges from less than 1 g in small consumer electronics to about 1 kg in electric vehicles (EVs) and hybrid and electric vehicles (HEVs), and can be as large as 1000-2000 kg in the generators of modern wind turbines. NdFeB permanent magnets contain about 31-32 wt% of rare-earth elements (REEs). Recycling of REEs contained in this type of magnets from the End-of-Life (EOL) products will play an important and complementary role in the total supply of REEs in the future. However, collection and recovery of the magnets from small consumer electronics imposes great social and technological challenges. This paper gives an overview of the sources of NdFeB permanent magnets related to their applications, followed by a summary of the various available technologies to recover the REEs from these magnets, including physical processing and separation, direct alloy production, and metallurgical extraction and recovery. At present, no commercial operation has been identified for recycling the EOL NdFeB permanent magnets and the recovery of the associated REE content. Most of the processing methods are still at various research and development stages. It is estimated that in the coming 10-15 years, the recycled REEs from EOL permanent magnets will play a significant role in the total REE supply in the magnet sector, provided that efficient technologies will be developed and implemented in practice.
引用
收藏
页码:122 / 149
页数:28
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