Direct current sputtered aluminum-doped zinc oxide films for thin crystalline silicon heterojunction solar cell

被引:9
作者
Qiu, Yu [1 ]
Hermawan, Henrico [1 ]
Gordon, Ivan [1 ]
Poortmans, Jef [1 ]
机构
[1] IMEC, B-3001 Louvain, Belgium
关键词
Oxides; Thin films; Sputtering; Electrical properties; Optical properties; PULSED-LASER DEPOSITION; ZNO FILMS; ROOM-TEMPERATURE; TRANSPARENT; PRESSURE; ELECTRODES;
D O I
10.1016/j.matchemphys.2013.06.002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The high-power high-throughput direct current (DC) magnetron sputtering of aluminum-doped zinc oxide (AZO) film was investigated for fabricating amorphous silicon/crystalline silicon heterojunction solar cells. The AZO films were deposited using 1.0 wt.% and 2.0 wt.% Al-doped ZnO targets. The functional properties of the deposited films were characterized by measuring the electrical conductivity, Hall mobility, free carrier density and optical transparency. The influence of the sputtering power, oxygen concentration, substrate temperature, post-annealing and film thickness on the film properties were studied systematically. The oxygen in the sputtering gas deteriorates the electrical and optical performance of AZO films, which can be improved by post annealing. An optimal value of 1.0 x 10(-3) Omega cm for the resistivity and 90% for the optical transmission was obtained at processing temperatures below 250 degrees C. Two types of thin Si heterojunction solar cells were prepared and compared using DC sputtered AZO film as the front electrode. Results show that DC sputtered AZO films meet the requirements for use as transparent front electrode in thin Si heterojunction solar cells. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:744 / 751
页数:8
相关论文
共 32 条
  • [1] Low resistivity transparent conducting Al-doped ZnO films prepared by pulsed laser deposition
    Agura, H
    Suzuki, A
    Matsushita, T
    Aoki, T
    Okuda, M
    [J]. THIN SOLID FILMS, 2003, 445 (02) : 263 - 267
  • [2] [Anonymous], 2009, NANOMARKETS REPORT I
  • [3] Effects of thickness and annealing on the properties of Ti-doped ZnO films by radio frequency magnetron sputtering
    Chang, Hung-Peng
    Wang, Fang-Hsing
    Chao, Jen-Chi
    Huang, Chia-Cheng
    Liu, Han-Wen
    [J]. CURRENT APPLIED PHYSICS, 2011, 11 (01) : S185 - S190
  • [4] The correlation between preferred orientation and performance of ITO thin films
    Chen, Yao
    Zhou, Yuqin
    Zhang, Qunfang
    Zhu, Meifang
    Liu, Fengzhen
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2007, 18 (Suppl 1) : S411 - S414
  • [5] Boron-doped a-Si:H/c-Si interface passivation:: Degradation mechanism
    De Wolf, Stefaan
    Kondo, Michio
    [J]. APPLIED PHYSICS LETTERS, 2007, 91 (11)
  • [6] Epitaxy-free monocrystalline silicon thin film: first steps beyond proof-of-concept solar cells
    Depauw, V.
    Qiu, Y.
    Van Nieuwenhuysen, K.
    Gordon, I.
    Poortmans, J.
    [J]. PROGRESS IN PHOTOVOLTAICS, 2011, 19 (07): : 844 - 850
  • [7] Effect of thermal annealing on ZnO:hAl thin films grown by spray pyrolysis
    El Manouni, A.
    Manjon, F. J.
    Perales, M.
    Mollar, M.
    Mari, B.
    Lopez, M. C.
    Barrado, J. R. Ramos
    [J]. SUPERLATTICES AND MICROSTRUCTURES, 2007, 42 (1-6) : 134 - 139
  • [8] Structural and functional properties of Al:ZnO thin films grown by Pulsed Laser Deposition at room temperature
    Gondoni, P.
    Ghidelli, M.
    Di Fonzo, F.
    Russo, V.
    Bruno, P.
    Marti-Rujas, J.
    Bottani, C. E.
    Bassi, A. Li
    Casari, C. S.
    [J]. THIN SOLID FILMS, 2012, 520 (14) : 4707 - 4711
  • [9] Gordon I., 2010, Proceedings of the 25th European Photovoltaic Solar Energy Conference and Exhibition and the 5th World Conference on Photovoltaic Energy Conversion, P3651
  • [10] Structural, electrical and optical properties of aluminum doped zinc oxide films prepared by radio frequency magnetron sputtering
    Kim, KH
    Park, KC
    Ma, DY
    [J]. JOURNAL OF APPLIED PHYSICS, 1997, 81 (12) : 7764 - 7772